Removal of organic compounds from olive mill wastewater using an eco-friendly adsorbent: Characterization, kinetics, isotherms, thermodynamics, and interaction analysis

被引:1
作者
Ammari, Malika [1 ]
Zerrouk, Mohammed [2 ]
Zoufri, Imane [1 ]
El-Byari, Younesse [1 ]
Mazrha, Abdelhadi [1 ]
Mrizak, Fatima Ez-zahrae [1 ]
Merzouki, Mohammed [1 ]
机构
[1] Univ Sidi Mohamed Ben Abdellah, Hlth Fac Sci, Lab Biotechnol Environm Agrifood, Fes 30000, Morocco
[2] Univ Sidi Mohamed Ben Abdellah, Fac Sci, Engn Lab Organometall Mol Mat & Environm, Fes 30000, Morocco
关键词
Adsorption; Clinker; Olive Mill Wastewater; Organic compound; AQUEOUS-SOLUTION; PERFORMANCE; ELECTROCOAGULATION; ADSORPTION; EFFICIENCY;
D O I
10.1016/j.sciaf.2025.e02612
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The use of clinker as a filtering medium is a new method for treating the waste water from olive mills (OMWW), which is a highly toxic effluent for the environment due to its high organic load and its huge concentration of phenolic compounds as confirmed by HPLC analysis. Scanning electron microscopy (SEM), Energy-dispersed X-rays (EDX), Brunauer-Emmet-Teller (BET) and Fourier transformed infrared spectroscopy (FTIR) were used to characterize the prepared clinker. Additionally, adsorption tests were conducted to evaluate the performance of the clinker. The adsorption study was carried out under different conditions such as contact time, pH value, adsorbate concentration and temperature. The adsorption mechanisms are described using the Langmuir, Freundlich, and Temkin isotherms, the pseudo-first-order and pseudo-second-order models represent the kinetics while the thermodynamic study of adsorption examines how thermodynamic properties influence the adsorption process. The results indicate that the pseudosecond-order model and the Freundlich isotherm are most suitable for the adsorption of OMWW. The results showed that the clinker can adsorb 1001.61 mg/g at an initial concentration of 5000 mg/L.
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页数:15
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