Halogenation of arenes using alkali metal halides/Fe(NO3)3<middle dot>9H2O at room temperature

被引：0

作者：

Li, Caicui ^{[1
,2
]}

Cheng, Yao ^{[2
]}

Pang, Fudan ^{[2
]}

Yan, Xiushuo ^{[2
]}

Huang, Zhengtao ^{[2
]}

Wang, Xinmei ^{[2
]}

Wang, Xiaodan ^{[1
,2
]}

Li, Yiying ^{[3
]}

Wang, Jinhui ^{[1
,2
]}

Xu, Huanjun ^{[2
]}

机构：

[1] HarBin Med Univ, Coll Pharm, Dept Med Chem & Nat Med Chem, Harbin, Peoples R China

[2] Qiongtai Normal Univ, Sch Sci, Haikou 571127, Peoples R China

[3] Hainan Med Univ, Sch Basic Med & Life Sci, Key Lab Brain Sci Res Transformat Trop Environm Ha, Key Lab Trop Translat Med,Minist Educ, Haikou, Peoples R China

来源：

RSC ADVANCES | 2025年 / 15卷 / 11期

基金：

海南省自然科学基金; 中国国家自然科学基金;

关键词：

SELECTIVE BROMINATION; EFFICIENT; CATALYSIS;

D O I：

10.1039/d5ra00837a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple, efficient and environmentally friendly methodology for the halodecarboxylation of anisole analogues using Fe(NO3)3<middle dot>9H2O/KBr or NaI at room temperature was developed. In this method, most substrates with an electron-donating group afforded corresponding products in good to excellent yields, whereas those with an electron-withdrawing group afforded low to moderate yields. More importantly, this protocol was also applicable for gram-scale synthesis. It is hoped that this methodology will be highly useful in organic synthesis.

引用

页码：8523 / 8528

页数：6

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