First comb-like copolymer of poly(ethyl 2-cyanoacrylate) grafted as a side-chain to dextran

被引：0
|
作者：
Dyatlov, Valery A. [1 ]
Seregina, Tatiana S. [1 ]
Derevnin, Igor A. [1 ]
Krivoborodov, Efrem G. [1 ]
Belyaeva, Anna A. [2 ]
Malashicheva, Anna B. [2 ]
V. Dyatlov, Alexander [3 ]
机构：
[1] DI Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia
[2] Russian Acad Sci, Inst Cytol, St Petersburg 194064, Russia
[3] Hebrew Univ Jerusalem, IL-9112001 Jerusalem, Israel
来源：
MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 06期
关键词：
ethyl; 2-cyanoacrylate; dextran; polysaccharides; anionic polymerization; comb-like graft copolymer; MALDI-TOF mass spectrometry; NANOCAPSULES;
D O I：
10.1016/j.mencom.2024.10.035
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first comb-like cyanoacrylic copolymer was synthesized by anionic polymerization of ethyl 2-cyanoacrylate in an aqueous solution of dextran of M w = 50 +/- 5 kDa. The copolymer was explored by NMR and Fourier IR spectroscopy, as well asby MALDI-TOF mass-spectrometry methods.It contains up to 10 cyanoacrylate units grafted to anhydroglucose cycles of dextran main chain, multi- substituted glycose units were not detected.
引用
收藏
页码：881 / 883
页数：3
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