Research progress on MXenes-based electrocatalysts with high oxygen activity for air cathodes in metal-air batteries

被引：3
作者：
Pan, Qiliang [1 ,2 ]
Fu, Lisan [1 ,3 ]
Wang, Zhouxiao [1 ,3 ]
Zhong, Zhengmin [1 ,2 ]
Zhao, Jianguo [1 ,2 ]
机构：
[1] Shanxi Datong Univ, Engn Res Ctr Coal Based Ecol Carbon Sequestrat Tec, Minist Educ, Datong 037009, Shanxi, Peoples R China
[2] Shanxi Datong Univ, Natl Forest & Grass Adm, Key Lab Graphene Forestry Applicat, Datong 037009, Shanxi, Peoples R China
[3] Shanxi Datong Univ, Coll Chem & Chem Engn, Datong 037009, Shanxi, Peoples R China
来源：
JOURNAL OF ENERGY STORAGE | 2025年 / 111卷
基金：
中国国家自然科学基金;
关键词：
MXenes; ORR; OER; Metal-air batteries; Catalyst; NONAQUEOUS LI-O-2 BATTERIES; LAYERED DOUBLE HYDROXIDE; NITROGEN-DOPED GRAPHENE; HIGH-PERFORMANCE; BIFUNCTIONAL CATALYST; REDUCTION REACTION; CARBON CATALYSTS; TI2C MXENE; MAX PHASE; LITHIUM;
D O I：
10.1016/j.est.2025.115388
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Metal-air batteries have attracted considerable attention due to their high theoretical capacity, low cost, and high safety. However, the slow kinetics of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) at the air electrode significantly hinder their commercial application. Since layered transition metal carbides and nitrides (MXenes) are extremely chemically stable, high conductors of electricity, and large surface areas, they find widespread applications in the field of energy storage and catalysis. Notably, when MXenes are composited with other nanocatalysts, their unique structure can enhance catalytic efficiency, accelerate electron transfer, and effectively inhibit aggregation. This improvement significantly boosts catalytic performance and offers a new pathway for optimizing the stability and performance of metal-air batteries. In this review, the preparation methods of MXenes are analyzed, and the synergistic effects of MXenes combined with different catalysts were innovatively explored, accelerating the activity of ORR and OER in various metal-air batteries. Combining theoretical calculations, the catalytic properties of different types of MXenes and their composite strategies with various catalysts are discussed to improve the performance of metal-air batteries. In addition, we prospectively analyzed the opportunities and challenges that MXenes may encounter in the future development of metal-air batteries, and provided some guidance suggestions for their commercial applications.
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页数：22
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