Visible-Light-Triggered Mn2(CO)10-Catalyzed Carbonylation of (Hetero)aryl Chlorides

被引：0

作者：

Yan, Yonggang ^{[1
,2
]}

Wang, Pengpeng ^{[1
,2
]}

Li, Shasha ^{[1
,2
]}

Dong, Jianyang ^{[1
,2
]}

Li, Gang ^{[1
,2
]}

Wang, Chao ^{[1
,2
]}

Xue, Dong ^{[1
,2
]}

机构：

[1] Shaanxi Normal Univ, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Peoples R China

[2] Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710119, Peoples R China

来源：

ORGANIC LETTERS | 2025年 / 27卷 / 02期

基金：

中国国家自然科学基金;

关键词：

PALLADIUM-CATALYZED CARBONYLATION; ARYL CHLORIDES; HALIDES; NUCLEOPHILES;

D O I：

10.1021/acs.orglett.4c04557

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbonylation of aryl electrophiles is an important method for constructing aromatic carbonyl compounds for materials science and pharmaceutical applications. However, there have been few studies on the carbonylation of abundant, inexpensive aryl chlorides. Moreover, the existing carbonylation methods usually require a high temperature, control of the CO pressure, and structurally complex catalysts and ligands. We herein report a mild, operationally simple method for visible-light-triggered amino- and alkoxycarbonylation of inert (hetero)aryl chlorides with Mn2(CO)10 as both a catalyst and solid CO source at room temperature. This method, which does not require external metal catalyst, photosensitizer, or CO gas, is also suitable for other coupling partners, including aryl bromide and iodide, phenol, or arylamine derivatives.

引用

页码：675 / 679

页数：5

共 35 条

[1] Pd/C-Catalyzed methoxycarbonylation of aryl chlorides [J].