All-Visible-Light-Activated Diarylethene Photoswitches

被引:0
作者
Li, Ruiji [1 ]
Ou, Tao [2 ]
Wen, Li [1 ]
Yan, Yehao [3 ]
Li, Wei [1 ]
Qin, Xulong [1 ]
Wang, Shouxin [1 ]
机构
[1] Jining Med Univ, Sch Pharm, Rizhao 276826, Peoples R China
[2] Binzhou Med Univ, Sch Pharm, Yantai 256603, Peoples R China
[3] Jining Med Univ, Sch Publ Hlth, Jining 272067, Peoples R China
来源
MOLECULES | 2024年 / 29卷 / 21期
关键词
photochromism; visible light; diarylethene; design strategy; INFRARED PHOTOCHROMIC BEHAVIOR; ANNIHILATION UP-CONVERSION; DUAL-MODE PHOTOCHROMISM; P-TYPES; DITHIENYLETHENE; PHOTOCYCLIZATION; MEMORIES; DERIVATIVES; MOLECULES; SWITCHES;
D O I
10.3390/molecules29215202
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Photochromic compounds have attracted much attention for their potential applications in photo-actuators, optoelectronic devices and optical recording techniques. This interest is driven by their key photochemical and photophysical properties, which can be reversibly modulated by light irradiation. Among them, diarylethene compounds have garnered extensive investigation due to their excellent thermal stability of both open- and closed-form isomers, robust fatigue resistance, high photocyclization quantum yield and good photochromic performance in both solution and solid phases. However, a notable limitation in expanding the utility of diarylethene compounds is the necessity for ultraviolet light to induce their photochromism. This requirement poses challenges, as ultraviolet light can be detrimental to biological tissues, and its penetration is often restricted in various media. This review provides an overview of design strategies employed in the development of visible-light-responsive diarylethene compounds. These design strategies serve as a guideline for molecular design, with the potential to significantly broaden the applications of all-visible-light-activated diarylethene compounds in the realms of materials science and biomedical science.
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页数:27
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