Synthesis, Structural Characterization and Catalytic Application of Ferrocenyl Based Bis(pyrazolyl) Palladium Complexes

被引：0

作者：

Meher, Sushanta Kumar ^{[1
]}

Aradhyula, Basava Punna Rao ^{[1
]}

Velpuri, Venkateswara Rao ^{[1
,2
]}

Venkatasubbaiah, Krishnan ^{[1
]}

机构：

[1] Natl Inst Sci Educ & Res NISER, OCC Homi Bhabha Natl Inst, Sch Chem Sci, Bhubaneswar 752050, Odisha, India

[2] Rajiv Gandhi Univ Knowledge Technol, Dept Chem, Vempalli 516330, Andhra Pradesh, India

来源：

CHEMPLUSCHEM | 2025年 / 90卷 / 01期

关键词：

Ferrocene; Bismuthanes; Palladium; Phosphine-free; Cross-coupling; CROSS-COUPLING REACTIONS; TRANSITION-METAL; DOMINO SYNTHESIS; N-PHENYLATION; ARYL; TRIARYLBISMUTHS; THREEFOLD; ARYLATION; REAGENTS; LIGANDS;

D O I：

10.1002/cplu.202400547

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report, synthesis of ferrocenyl based bis(pyrazolyl) palladium complexes. The catalytic utility of the complexes in the cross-coupling of triarylbismuthanes and aryl bromides was evaluated. Our ferrocenyl based palladium complex showed wide substrate scope for both triarylbismuthanes and aryl bromides. Further, the current catalytic system also showed superior activity over the well-established palladium-phosphine catalytic system using triarylbismuthanes as reagents.

引用

页数：5

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