Multifunctional nanoporous biocarbon derived from ginger: a promising material for CO2 capture and supercapacitor

被引:1
作者
Davidraj, Jefrin M. [1 ]
Sathish, C. I. [1 ]
Perumalsamy, Vibin [1 ]
Narayanan, Vishnumaya [1 ]
Wijerathne, Binodhya [2 ]
Yu, Xiaojiang [3 ]
Breese, Mark B. H. [3 ]
Ahmed, Muhammad Ibrar [1 ]
Yi, Jiabao [1 ]
Vinu, Ajayan [1 ]
机构
[1] Univ Newcastle, Coll Engn Sci & Environm, Global Innovat Ctr Adv Nanomat GICAN, Univ Dr, Callaghan, NSW 2308, Australia
[2] Queensland Univ Technol, Fac Sci, Sch Chem & Phys, Brisbane, Qld 4000, Australia
[3] Natl Univ Singapore, Singapore Synchrotron Light Source, Singapore 119260, Singapore
来源
ENERGY MATERIALS | 2025年 / 5卷 / 02期
基金
澳大利亚研究理事会;
关键词
Bio-waste; porous activated carbon; CO2; capture; supercapacitors; energy storage; EXCELLENT PERFORMANCE; SURFACE-AREA; ADSORPTION; GRAPHENE; CARBONS; NEXAFS; CAPACITY; NITROGEN;
D O I
10.20517/energymater.2024.94
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Nanoporous activated carbons derived from bio-waste are gaining consideration due to their exceptional potential for energy storage and CO2 adsorption. Herein, we put forward a straightforward, low-cost method for preparing a highly efficient nanoporous biocarbon from ginger using solid-state activation approach. Ginger was pyrolyzed at various temperatures before activating using different amounts of KOH as an activator to produce nanoporous biocarbon. The prepared samples possess high specific surface areas and large pore volumes. By simply adjusting the pyrolysis temperature, the microporosity and surface oxygen functionalities can be finely tuned. The best sample exhibits a high Brunauer-Emmett-Teller-specific surface area of 2,330 m2/g and a large pore volume of 1.10 cm3/g and offers excellent specific capacitance of 244 and 119 F/g when tested in a three-electrode and two- electrode, at a current density of 0.5 A/g. Additionally, the optimized material demonstrates a high CO2 uptake capacity of 4.87 mmol/g at ambient pressure and 25.8 mmol/g at 0 degrees C and 30 bar. These interesting adsorption and energy storage performances of the nanoporous biocarbon underscore the potential of converting food waste into high-performance CO2 adsorbents and supercapacitors.
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页数:14
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