sp2 Carbon-Conjugated Covalent Organic Frameworks (sp2c-COFs): Synthesis and Application in Photocatalytic Water Splitting

被引：0

作者：

Peng, Shiqiong ^{[1
]}

Wang, Renjie ^{[1
]}

Yang, Yao ^{[2
]}

Wang, Shuyan ^{[2
]}

Liang, En ^{[1
]}

Han, Bing ^{[1
]}

Li, Junbo ^{[2
]}

Yu, Xianglin ^{[1
]}

Zhang, Qichun ^{[3
,4
]}

机构：

[1] Wuhan Inst Technol, Sch Chem Engn & Pharm, Wuhan 430074, Peoples R China

[2] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430074, Peoples R China

[3] City Univ Hong Kong, Dept Mat Sci & Engn, Dept Chem, Ctr Super Diamond & Adv Films COSDAF, Hong Kong 999077, Peoples R China

[4] City Univ Hong Kong, Hong Kong Inst Clean Energy, Hong Kong 999077, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2025年

关键词：

conjugated covalent organic frameworks; hydrogen evolution and oxygen evolution reactions; photocatalytic water splitting; sp2; carbon-conjugated; synthesis; FUSED N-HETEROACENE; HYDROGEN; CRYSTALLINE; CONSTRUCTION; COF;

D O I：

10.1002/marc.202400967

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Preparation of irreversible sp2 carbon-conjugated covalent organic frameworks (sp2c-COFs) with specific porosity, easy structural functionalization, high chemical stability, and unique pi-electron conjugation structure (especially the combination of pi-pi stacking interactions and conjugation system), can remove the barrier of electron transfer and provide a unique advantage for photocatalytic water splitting. Herein, based on three kinds of reactions (Aldol condensation reaction, Knoevenagel condensation reaction, and Horner-Wadsworth-Emmons reaction) and guided by the precise modulation of ligand structure and topology, this review summarizes the synthesis of sp2c-COFs and their applications in photoelectrocatalytic water splitting (hydrogen evolution and oxygen evolution reactions). Furthermore, challenges and possible research directions for sp2c-COFs in photocatalytic water splitting are also provided.

引用

页数：35

共 166 条

[61] Macrocycle-on-COF photocatalyst constructed by in-situ linker exchange for efficient photocatalytic CO2 cycloaddition [J].

Li, Xiaojuan ;

Niu, Xinxin ;

Fu, Peng ;

Song, Yaru ;

Zhang, Enbing ;

Dang, Yanfeng ;

Yan, Jing ;

Feng, Guangyuan ;

Lei, Shengbin ;

Hu, Wenping .

APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2024, 350

[62] Highly stable β-ketoenamine-based covalent organic frameworks (COFs): synthesis and optoelectrical applications [J].

Li, Yaqin ;

Liu, Maosong ;

Wu, Jinjun ;

Li, Junbo ;

Yu, Xianglin ;

Zhang, Qichun .

FRONTIERS OF OPTOELECTRONICS, 2022, 15 (01)

[63] Three-Component Donor-?-Acceptor Covalent-Organic Frameworks for Boosting Photocatalytic Hydrogen Evolution [J].

Li, Ziping ;

Deng, Tianqi ;

Ma, Si ;

Zhang, Zhenwei ;

Wu, Gang ;

Wang, Jiaao ;

Li, Qizhen ;

Xia, Hong ;

Yang, Shuo-Wang ;

Liu, Xiaoming .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (15) :8364-8374

[64] Fabricating s-collidine-derived vinylene-linked covalent organic frameworks for photocatalysis [J].

Li, Zuyi ;

Wang, Wengjing ;

Tao, Feng ;

Zhou, Wenwen ;

Wang, Lianke ;

Yu, Zhipeng ;

Wang, Kaixuan ;

Zhang, Jie ;

Zhou, Hongping .

CHEMICAL COMMUNICATIONS, 2023, 59 (78) :11728-11731

[65] Nonlinear optical properties of porphyrin-based covalent organic frameworks determined by steric-orientation of conjugation [J].

Liang, Bin ;

Zhao, Jie ;

Wang, Jingjing ;

Li, Yunfei ;

Han, Bin ;

Li, Jie ;

Ding, Xu ;

Xie, Zheng ;

Wang, Hailong ;

Zhou, Shuyun .

JOURNAL OF MATERIALS CHEMISTRY C, 2023, 11 (09) :3354-3359

[66] Tetrazole-functionalized two-dimensional covalent organic frameworks coordinated with metal ions for electrocatalytic oxygen evolution reaction [J].

Liang, Ying ;

Xia, Tian ;

Wu, Zhuangzhuang ;

Yang, Yingjie ;

Li, Yongpeng ;

Sui, Zhuyin ;

Li, Chaokun ;

Fan, Ruimei ;

Tian, Xinlong ;

Chen, Qi .

MATERIALS TODAY CHEMISTRY, 2022, 24

[67] Rational Modification of Two-Dimensional Donor-Acceptor Covalent Organic Frameworks for Enhanced Visible Light Photocatalytic Activity [J].

Lin, Chenxiang ;

Liu, Xiaolin ;

Yu, Baoqiu ;

Han, Chaozheng ;

Gong, Lei ;

Wang, Chiming ;

Gao, Ying ;

Bian, Yongzhong ;

Jiang, Jianzhuang .

ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (23) :27041-27048

[68] Fully conjugated two-dimensional sp2-carbon covalent organic frameworks for efficient photocatalytic hydrogen generation [J].

Liu, Hui ;

Wang, Danbo ;

Yu, Zefang ;

Chen, Yajing ;

Li, Xubing ;

Zhang, Ruiling ;

Chen, Xiong ;

Wu, Lizhu ;

Ding, Naixiu ;

Wang, Yuancheng ;

Zhao, Yingjie .

SCIENCE CHINA-MATERIALS, 2023, 66 (06) :2283-2289

[69] In Situ Growth of Covalent Organic Framework Nanosheets on Graphene as the Cathode for Long-Life High-Capacity Lithium-Ion Batteries [J].

Liu, Xiaolin ;

Jin, Yucheng ;

Wang, Hailong ;

Yang, Xiya ;

Zhang, Pianpian ;

Wang, Kang ;

Jiang, Jianzhuang .

ADVANCED MATERIALS, 2022, 34 (37)

[70] Rational design of a phenothiazine-based donor-acceptor covalent organic framework for enhanced photocatalytic oxidative coupling of amines and cyclization of thioamides [J].

Liu, Yang ;

Jiang, Xinyue ;

Chen, Likun ;

Cui, Yan ;

Li, Qiu-Yan ;

Zhao, Xinsheng ;

Han, Xiguang ;

Zheng, Yong-Chao ;

Wang, Xiao-Jun .

JOURNAL OF MATERIALS CHEMISTRY A, 2023, 11 (03) :1208-1215

← 2 3 4 5 6 7 8 9 10 11 →