sp2 Carbon-Conjugated Covalent Organic Frameworks (sp2c-COFs): Synthesis and Application in Photocatalytic Water Splitting

被引：0
作者：
Peng, Shiqiong [1 ]
Wang, Renjie [1 ]
Yang, Yao [2 ]
Wang, Shuyan [2 ]
Liang, En [1 ]
Han, Bing [1 ]
Li, Junbo [2 ]
Yu, Xianglin [1 ]
Zhang, Qichun [3 ,4 ]
机构：
[1] Wuhan Inst Technol, Sch Chem Engn & Pharm, Wuhan 430074, Peoples R China
[2] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430074, Peoples R China
[3] City Univ Hong Kong, Dept Mat Sci & Engn, Dept Chem, Ctr Super Diamond & Adv Films COSDAF, Hong Kong 999077, Peoples R China
[4] City Univ Hong Kong, Hong Kong Inst Clean Energy, Hong Kong 999077, Peoples R China
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2025年
关键词：
conjugated covalent organic frameworks; hydrogen evolution and oxygen evolution reactions; photocatalytic water splitting; sp2; carbon-conjugated; synthesis; FUSED N-HETEROACENE; HYDROGEN; CRYSTALLINE; CONSTRUCTION; COF;
D O I：
10.1002/marc.202400967
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Preparation of irreversible sp2 carbon-conjugated covalent organic frameworks (sp2c-COFs) with specific porosity, easy structural functionalization, high chemical stability, and unique pi-electron conjugation structure (especially the combination of pi-pi stacking interactions and conjugation system), can remove the barrier of electron transfer and provide a unique advantage for photocatalytic water splitting. Herein, based on three kinds of reactions (Aldol condensation reaction, Knoevenagel condensation reaction, and Horner-Wadsworth-Emmons reaction) and guided by the precise modulation of ligand structure and topology, this review summarizes the synthesis of sp2c-COFs and their applications in photoelectrocatalytic water splitting (hydrogen evolution and oxygen evolution reactions). Furthermore, challenges and possible research directions for sp2c-COFs in photocatalytic water splitting are also provided.
引用
收藏
页数：35
相关论文
共 166 条
[1]   Vinylene-Linked Covalent Organic Frameworks by Base-Catalyzed Aldol Condensation [J].
Acharjya, Amitava ;
Pachfule, Pradip ;
Roeser, Jerome ;
Schmitt, Franz-Josef ;
Thomas, Arne .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (42) :14865-14870
[2]   Cobalt coordinated two-dimensional covalent organic framework a sustainable and robust electrocatalyst for selective CO2 electrochemical conversion to formic acid [J].
Ali, Sajjad ;
Iqbal, Rashid ;
Wahid, Fazli ;
Ismail, Pir Muhammad ;
Saleem, Adil ;
Ali, Sharafat ;
Raziq, Fazal ;
Ullah, Sami ;
Ullah, Ihsan ;
Tahir ;
Zahoor, Muhammad ;
Wu, Xiaoqiang ;
Xiao, Haiyan ;
Zu, Xiaotao ;
Qiao, Liang .
FUEL PROCESSING TECHNOLOGY, 2022, 237
[3]   Covalent Organic Frameworks with trans-Dimensionally Vinylene-linked π-Conjugated Motifs [J].
Bi Shuai ;
Meng Fancheng ;
Zhang Zixing ;
Wu Dongqing ;
Zhang Fan .
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2022, 38 (02) :382-395
[4]   Synthesis of Vinylene-Linked Covalent Organic Frameworks by Monomer Self-Catalyzed Activation of Knoevenagel Condensation [J].
Bi, Shuai ;
Meng, Fancheng ;
Wu, Dongqing ;
Zhang, Fan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (08) :3653-3659
[5]   Vinylene-Bridged Two-Dimensional Covalent Organic Frameworks via Knoevenagel Condensation of Tricyanomesitylene [J].
Bi, Shuai ;
Thiruvengadam, Palani ;
Wei, Shice ;
Zhang, Wenbei ;
Zhang, Fan ;
Gao, Lusha ;
Xu, Junsong ;
Wu, Dongqing ;
Chen, Jie-Sheng ;
Zhang, Fan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (27) :11893-11900
[6]   Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms [J].
Bi, Shuai ;
Yang, Can ;
Zhang, Wenbei ;
Xu, Junsong ;
Liu, Lingmei ;
Wu, Dongqing ;
Wang, Xinchen ;
Han, Yu ;
Liang, Qifeng ;
Zhang, Fan .
NATURE COMMUNICATIONS, 2019, 10 (1)
[7]   Substantial Cyano-Substituted Fully sp2-Carbon-Linked Framework: Metal-Free Approach and Visible-Light-Driven Hydrogen Evolution [J].
Bi, Shuai ;
Lan, Zhi-An ;
Paasch, Silvia ;
Zhang, Wenbei ;
He, Yafei ;
Zhang, Chao ;
Liu, Feng ;
Wu, Dongqing ;
Zhuang, Xiaodong ;
Brunner, Eike ;
Wang, Xinchen ;
Zhang, Fan .
ADVANCED FUNCTIONAL MATERIALS, 2017, 27 (39)
[8]   Controlled Synthesis of Crystalline Metalated Porphyrin Covalent Organic Frameworks through an Assembler Approach [J].
Bourda, Laurens ;
Dansette, Isaac ;
Jena, Himanshu Sekhar ;
Chen, Hui ;
Raza, Asif ;
Vrielinck, Henk ;
Van Hecke, Kristof ;
Van Der Voort, Pascal ;
Krishnaraj, Chidharth .
CHEMISTRY OF MATERIALS, 2024, 36 (19) :9526-9534
[9]   Synthesis and Acid-Responsive Properties of a Highly Porous Vinylene-Linked Covalent Organic Framework [J].
Bu, Ran ;
Zhang, Lin ;
Liu, Xiao-Yan ;
Yang, Shuai-Liang ;
Li, Gen ;
Gao, En-Qing .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (22) :26431-26440
[10]   Amidoxime-functionalized covalent organic framework as simultaneous luminescent sensor and adsorbent for organic arsenic from water [J].
Chen, Hui ;
Liu, Wanlu ;
Cheng, Long ;
Meledina, Maria ;
Meledin, Alexander ;
Van Deun, Rik ;
Leus, Karen ;
van der Voort, Pascal .
CHEMICAL ENGINEERING JOURNAL, 2022, 429
12345678910