Cobalt-Catalyzed Regioselective Hydroformylation of Allylic Alcohol Esters

被引：0

作者：

Du, Zhenhao ^{[1
]}

Lu, Wenxin ^{[2
]}

Chong, Qinglei ^{[1
]}

Meng, Fanke ^{[1
,3
,4
]}

机构：

[1] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[3] Univ Chinese Acad Sci, Hangzhou Inst Adv Study, Sch Chem & Mat Sci, 1 Sublane Xiangshan, Hangzhou 310024, Peoples R China

[4] Beijing Natl Lab Mol Sci, Zhongguancun North First St, Beijing 100871, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2025年 / 57卷 / 16期

基金：

中国国家自然科学基金;

关键词：

hydroformylation; synthesis gas; cobalt; functionalized olefins; allyl alcohol derivatives; ALDEHYDES; CARBONYL; ALKENES; LIGANDS; METALS; REGIO;

D O I：

10.1055/a-2515-0227

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aliphatic aldehydes are important building blocks in organ-ic synthesis due to their high reactivity and versatility. Herein, we reporta simple, mild and efficient method for the hydroformylation of allyl al-cohol esters under cobalt catalysis. This procedure offers good func-tional group tolerance, moderate to good product yields and exclusivechemo- and regioselectivity, making it an attractive method to preparealdehydes with linear selectivity.

引用

页码：2434 / 2443

页数：10