Cobalt-Catalyzed Regioselective Hydroformylation of Allylic Alcohol Esters

被引：0

作者：

Du, Zhenhao ^{[1
]}

Lu, Wenxin ^{[2
]}

Chong, Qinglei ^{[1
]}

Meng, Fanke ^{[1
,3
,4
]}

机构：

[1] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[3] Univ Chinese Acad Sci, Hangzhou Inst Adv Study, Sch Chem & Mat Sci, 1 Sublane Xiangshan, Hangzhou 310024, Peoples R China

[4] Beijing Natl Lab Mol Sci, Zhongguancun North First St, Beijing 100871, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2025年 / 57卷 / 16期

基金：

中国国家自然科学基金;

关键词：

hydroformylation; synthesis gas; cobalt; functionalized olefins; allyl alcohol derivatives; ALDEHYDES; CARBONYL; ALKENES; LIGANDS; METALS; REGIO;

D O I：

10.1055/a-2515-0227

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aliphatic aldehydes are important building blocks in organ-ic synthesis due to their high reactivity and versatility. Herein, we reporta simple, mild and efficient method for the hydroformylation of allyl al-cohol esters under cobalt catalysis. This procedure offers good func-tional group tolerance, moderate to good product yields and exclusivechemo- and regioselectivity, making it an attractive method to preparealdehydes with linear selectivity.

引用

页码：2434 / 2443

页数：10

共 42 条

[1] From alkenes to alcohols by cobalt-catalyzed hydroformylation-reduction [J].

Achonduh, George ;

Yang, Qian ;

Alper, Howard .

TETRAHEDRON, 2015, 71 (08) :1241-1246

[2] High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects [J].

Boogaerts, Ine I. F. ;

White, Daniel F. S. ;

Cole-Hamilton, David J. .

CHEMICAL COMMUNICATIONS, 2010, 46 (13) :2194-2196

[3]

Borner A., 2016, HYDROFORMYLATION FUN

[4] Recent Developments in the Scope, Practicality, and Mechanistic Understanding of Enantioselective Hydroformylation [J].

Brezny, Anna C. ;

Landis, Clark R. .

ACCOUNTS OF CHEMICAL RESEARCH, 2018, 51 (09) :2344-2354

[5] Bicyclic phosphines as ligands for cobalt-catalysed hydroformylation [J].

Crause, C ;

Bennie, L ;

Damoense, L ;

Dwyer, CL ;

Grove, C ;

Grimmer, N ;

van Rensburg, WJ ;

Kirk, MM ;

Mokheseng, KM ;

Otto, S ;

Steynberg, PJ .

DALTON TRANSACTIONS, 2003, (10) :2036-2042

[6] Cobalt-catalysed hydroformylation of epoxides in the presence of phosphine oxides [J].

Delolo, Fabio G. ;

Kubis, Christoph ;

Zhang, Baoxin ;

Neumann, Helfried ;

dos Santos, Eduardo N. ;

Gusevskaya, Elena V. ;

Beller, Matthias .

CATALYSIS SCIENCE & TECHNOLOGY, 2024, 14 (06) :1524-1533

[7] Cobalt-Catalyzed Hydroformylation under Mild Conditions in the Presence of Phosphine Oxides [J].

Delolo, Fabio G. ;

Yang, Ji ;

Neumann, Helfried ;

dos Santos, Eduardo N. ;

Gusevskaya, Elena, V ;

Beller, Matthias .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (14) :5148-5154

[8]

Evans D., 1968, J CHEM SOC A, V3133

[9] Applied Hydroformylation [J].

Franke, Robert ;

Selent, Detlef ;

Boerner, Armin .

CHEMICAL REVIEWS, 2012, 112 (11) :5675-5732

[10] Cobalt-Catalyzed Hydroformylation of Alkenes: Generation and Recycling of the Carbonyl Species, and Catalytic Cycle [J].

Hebrard, Frederic ;

Kalck, Philippe .

CHEMICAL REVIEWS, 2009, 109 (09) :4272-4282

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