Calcium Carbonate as Dephosphorization Agent in Direct Reduction Roasting of High-Phosphorus Oolitic Iron Ore: Reaction Behavior, Iron Recovery, and Dephosphorization Mechanism

被引:0
作者
Chen, Chong [1 ]
Wu, Shichao [2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Civil & Resource Engn, Beijing 100083, Peoples R China
[2] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Peoples R China
关键词
high-phosphorus oolitic iron ore; calcium carbonate; direct reduction roasting; reaction behavior; dephosphorization mechanism; MAGNETIC SEPARATION; HEMATITE ORE; FE; REMOVAL; NA2CO3;
D O I
10.3390/min14101023
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
Calcium carbonate, renowned for its affordability and potent dephosphorization capabilities, finds widespread use as a dephosphorization agent in the direct reduction roasting of high-phosphorus oolitic hematite (HPOIO). However, its precise impact on iron recovery and the dephosphorization of iron minerals with phosphorus within HPOIO, particularly the mineral transformation rule and dephosphorization mechanism, remains inadequately understood. This study delves into the nuanced effects of calcium carbonate on iron recovery and dephosphorization through direct reduction roasting and magnetic separation. A direct reduction iron (DRI) boasting 95.57% iron content, 93.94% iron recovery, 0.08% phosphorus content, and an impressive 92.08% dephosphorization is achieved. This study underscores how the addition of calcium carbonate facilitates the generation of apatite from phosphorus in iron minerals and catalyzes the formation of gehlenite by reacting with silicon dioxide and alumina, inhibiting apatite reduction. Furthermore, it increases the liquid phase, enhancing the dissociation of metallic iron monomers during the grinding procedure, thus facilitating efficient dephosphorization.
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页数:16
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