Development of CZTS thin film solar cell with a buffer layer formed by the sputtering ZnO followed by sulfurization

被引:0
作者
Shimamune, Yosuke [1 ]
Jimbo, Kazuo [1 ]
机构
[1] Natl Inst Technol KOSEN, Nagaoka Coll, Nagaoka, Niigata 9408532, Japan
关键词
CZTS solar cell; ZnO; buffer; CHEMICAL BATH DEPOSITION; CDS BUFFER; FUTURE-PROSPECTS; CU2ZNSNS4; OPTIMIZATION; EFFICIENCY; DEVICE;
D O I
10.35848/1347-4065/adc011
中图分类号
O59 [应用物理学];
学科分类号
摘要
In this study, a buffer layer formed using the sputtering of ZnO followed by sulfurization is investigated to install into the Cu2ZnSnS4 (CZTS) solar cells. A buffer layer connects a light absorption layer and a window layer and it works as a separator of carriers. Therefore, its influence on solar cell performance is very severe. We aim to realize the simple full dry process for the production of CZTS solar cells without a wet process. CZTS is formed by RF sputtering using a Cu-Zn-Sn-S sintered target followed by sulfurization using H2S/N2 gases. The sulfurized ZnO buffer layer is formed by RF sputtering and following sulfurization using H2S/N2 gases. An Al-doped ZnO layer as a window layer is applied to the solar cells. In this report, the optical and structural characteristics of sulfurized ZnO and its influence on solar cell performance are investigated.
引用
收藏
页数:6
相关论文
共 39 条
[1]  
Aaron D., 2012, Appl. Phys. Lett, V100, DOI [10.1063/1.4714737, DOI 10.1063/1.4714737]
[2]   Enhancement of the conversion efficiency of Cu2ZnSnS4 thin film solar cell through the optimization of some device parameters [J].
Adewoyin, Adeyinka D. ;
Olopade, Muteeu A. ;
Chendo, Micheal .
OPTIK, 2017, 133 :122-131
[3]   Cadmium-Free Kesterite Thin-Film Solar Cells with High Efficiency Approaching 12% [J].
Ahmad, Nafees ;
Zhao, Yunhai ;
Ye, Fan ;
Zhao, Jun ;
Chen, Shuo ;
Zheng, Zhuanghao ;
Fan, Ping ;
Yan, Chang ;
Li, Yingfen ;
Su, Zhenghua ;
Zhang, Xianghua ;
Liang, Guangxing .
ADVANCED SCIENCE, 2023, 10 (26)
[4]   Understanding the effect of the carbon on the photovoltaic properties of the Cu2ZnSnS4 [J].
Ahmoum, Hassan ;
Boughrara, Mourad ;
Su'ait, Mohd Sukor ;
Li, Guojian ;
Chopra, Siddheshwar ;
Wang, Qiang ;
Kerouad, Mohamed .
MATERIALS CHEMISTRY AND PHYSICS, 2020, 251
[5]   Impact of Minor Phases on the Performances of CZTSSe Thin-Film Solar Cells [J].
Altamura, Giovanni ;
Vidal, Julien .
CHEMISTRY OF MATERIALS, 2016, 28 (11) :3540-3563
[6]   Comparative studies of CdS thin films by chemical bath deposition techniques as a buffer layer for solar cell applications [J].
Ashok, A. ;
Regmi, G. ;
Romero-Nunez, A. ;
Solis-Lopez, M. ;
Velumani, S. ;
Castaneda, H. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2020, 31 (10) :7499-7518
[7]   Preparation and evaluation of Zn(O,S) thin film layer by sulfurization method [J].
Bahrudin, M. S. ;
Arsad, A. Z. ;
Abdullah, S. F. ;
Azman, N., I ;
Chau, C. F. ;
Ahmad, I. ;
Adini, W. S. W. ;
Zuhdi, A. W. Mahmood ;
Abdullah, W. S. Wan .
MATERIALS LETTERS, 2023, 349
[8]   Cd-free buffer layer materials on Cu2ZnSn(SxSe1-x)4: Band alignments with ZnO, ZnS, and In2S3 [J].
Barkhouse, D. Aaron R. ;
Haight, Richard ;
Sakai, Noriyuki ;
Hiroi, Homare ;
Sugimoto, Hiroki ;
Mitzi, David B. .
APPLIED PHYSICS LETTERS, 2012, 100 (19)
[9]   Numerical study of CZTS/CZTSSe tandem thin film solar cell using SCAPS-1D [J].
Benzetta, Abd Elhalim ;
Abderrezek, Mahfoud ;
Djeghlal, Mohammed Elamine .
OPTIK, 2021, 242 (242)
[10]   Reduced band gap and diffusion controlled spherical n-type ZnS nanoparticles for absorption of UV-Vis region of solar spectrum [J].
Bhushan, Medha ;
Jha, Ranjana ;
Bhardwaj, Rekha .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2019, 135