Construction of SnO2 nanoparticles modified Bi/MoO3 nanosheets heterojunctions for fast response and highly selective ethanol sensing performance

被引:1
作者
Yang, Huihong [1 ]
Liu, Chenhui [1 ]
Liu, Linping [1 ]
Chuan, Jinrong [1 ]
Gao, Jiyun [1 ]
Duan, Shengzhi [1 ]
机构
[1] Yunnan Minzu Univ, Sch Chem & Environm, Kunming 650500, Peoples R China
关键词
SnO2-Bi/MoO3; Ethanol gas sensor; Heterojunction; Gas sensing mechanism; HYDROTHERMAL SYNTHESIS; MOO3; NANOBELTS; GAS; OXIDE; NANORODS; HETEROSTRUCTURES; ALPHA-MOO3; SENSOR; NANOSTRUCTURES; DEPOSITION;
D O I
10.1016/j.jallcom.2025.178977
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The metal oxide semiconductor material molybdenum oxide (alpha-MoO3) is one of the current research hotspots for gas-sensitive materials. Studies have shown that the current gas-sensitive sensor elements of pure phase alpha-MoO3 materials still have disadvantages: they operate at high temperatures, are unstable, and take a long time to respond. To improve the above mentioned drawbacks, SnO2-Bi/MoO3 composites for ethanol gas sensors were synthesized in this paper by a simple hydrothermal method and liquid phase chemical method. The surface of Bi/ MoO3 composites was uniformly covered with SnO2 nanoparticles to enhance their specific surface area. The Bi/ MoO3 nanoribbons functioned as channels for electron transfer, creating a linkage among the SnO2 nanoparticles. At 300 degrees C, the SnO2-Bi/MoO3 (wt%: 15 %) responded to 100 ppm ethanol was up to 26.39. The measured value was approximately 3.93 times higher compared to MoO3 (response = 6.72, temperature = 300 degrees C) and 2.20 times greater than Bi/MoO3 (12.01). In addition, the heterojunction materials of SnO2-Bi/MoO3 (wt%: 15 %) respond quickly, are selective, and stable among these composites. The mechanism of gas sensing was thoroughly examined with respect to the ability of carrier transfer, the synergistic interaction between SnO2 and MoO3, the effects of heterojunctions, and improvements in morphology. Here, a sensor utilizing a ternary nanocomposite comprising SnO2-Bi/MoO3 is reported, and its enhanced sensing performance highlights the fact that the SnO2Bi/MoO3 material has a narrow bandgap, abundant surface vacancies and highly active sites. A straightforward approach is presented for creating MOS-based nanocomposites aimed at the efficient identification of ethanol.
引用
收藏
页数:16
相关论文
共 86 条
[1]   Selective Discrimination of VOCs Applying Gas Sensing Kinetic Analysis over a Metal Oxide-Based Chemiresistive Gas Sensor [J].
Acharyya, Snehanjan ;
Nag, Sudip ;
Kimbahune, Sanjay ;
Ghose, Avik ;
Pal, Arpan ;
Guha, Prasanta Kumar .
ACS SENSORS, 2021, 6 (06) :2218-2224
[2]   Strong effects of gallia on structure and selective responses of Ga2O3-In2O3 nanocomposite sensors to either ethanol, CO or CH4 [J].
Bagheri, Minoo ;
Khodadadi, Abbas Ali ;
Mahjoub, Ali Reza ;
Mortazavi, Yadollah .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 220 :590-599
[3]   Pine dendritic bismuth vanadate loaded on reduced graphene oxide for detection of low concentration triethylamine [J].
Bai, Shouli ;
Sun, Lixia ;
Sun, Jianhua ;
Han, Jingyi ;
Zhang, Kewei ;
Li, Qiangqiang ;
Luo, Ruixian ;
Li, Dianqing ;
Chen, Aifan .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 587 :183-191
[4]   Intrinsic characteristic and mechanism in enhancing H2S sensing of Cd-doped α-MoO3 nanobelts [J].
Bai, Shouli ;
Chen, Chao ;
Zhang, Dongfeng ;
Luo, Ruixian ;
Li, Dianqing ;
Chen, Aifan ;
Liu, Chung-Chiun .
SENSORS AND ACTUATORS B-CHEMICAL, 2014, 204 :754-762
[5]   Ultrasonic synthesis of MoO3 nanorods and their gas sensing properties [J].
Bai, Shouli ;
Chen, Song ;
Chen, Liangyuan ;
Zhang, Kewei ;
Luo, Ruixian ;
Li, Dianqing ;
Liu, Chung Chiun .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 174 :51-58
[6]   Ethanol sensing behavior of Pd-nanoparticles decorated ZnO-nanorod based chemiresistive gas sensors [J].
Cao, P. ;
Yang, Z. ;
Navale, S. T. ;
Han, S. ;
Liu, X. ;
Liu, W. ;
Lu, Y. ;
Stadler, F. J. ;
Zhu, D. .
SENSORS AND ACTUATORS B-CHEMICAL, 2019, 298
[7]   Optimization ethanol detection performance manifested by gas sensor based on In2O3/ZnS rough microspheres [J].
Chen, Q. ;
Ma, S. Y. ;
Xu, X. L. ;
Jiao, H. Y. ;
Zhang, G. H. ;
Liu, L. W. ;
Wang, P. Y. ;
Gengzang, D. J. ;
Yo, H. H. .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 264 :263-278
[8]   ZIF-8 derived hexagonal-like α-Fe2O3/ZnO/Au nanoplates with tunable surface heterostructures for superior ethanol gas-sensing performance [J].
Chen, Ying ;
Li, Hui ;
Ma, Qian ;
Che, Quande ;
Wang, Junpeng ;
Wang, Gang ;
Yang, Ping .
APPLIED SURFACE SCIENCE, 2018, 439 :649-659
[9]   MOF-derived SnO2@ZnO ethanol sensors with enhanced gas sensing properties [J].
Cheng, Yuyang ;
Shao, Tingting ;
Dong, Juntang ;
Kou, Huirong ;
Zhang, Fuchun ;
Guo, Jiaming ;
Liu, Xingxing .
VACUUM, 2023, 216
[10]   Cr2O3 nanoparticle-functionalized WO3 nanorods for ethanol gas sensors [J].
Choi, Seungbok ;
Bonyani, Maryam ;
Sun, Gun-Joo ;
Lee, Jae Kyung ;
Hyun, Soong Keun ;
Lee, Chongmu .
APPLIED SURFACE SCIENCE, 2018, 432 :241-249