Impact of Eu3+/Y3+doping on the structural and optical properties of SrTiO3 perovskite phosphor and multi-functional applications

被引:4
作者
Upadhyay, Satyam [1 ]
Dwivedi, Arpita [2 ]
Yadav, Prateek Kumar [1 ]
Srivastava, Monika [2 ]
Srivastava, Amit [3 ]
Upadhyay, Chandan [2 ]
Srivastava, S. K. [1 ]
机构
[1] Banaras Hindu Univ, Inst Sci, Dept Phys, Varanasi 221005, India
[2] Banaras Hindu Univ, Indian Inst Technol, Sch Mat Sci & Technol, Varanasi, India
[3] VBS Purvanchal Univ, Dept Phys, TDPG Coll, Jaunpur 222001, India
关键词
Latent fingerprints; Anti-counterfeiting; Photoluminescence; LEDs; Forensic; CIE; Perovskite; FINGERPRINT RECOGNITION; HYDROTHERMAL SYNTHESIS; LATENT FINGERPRINTS; DOPED SRTIO3; PHOTOLUMINESCENCE; VISUALIZATION; SPECTRA; NANOPHOSPHORS; FILMS; ND3+;
D O I
10.1016/j.jallcom.2025.178866
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A latent fingerprint (LFP) examination is essential for identifying fingerprints at crime sites, and personal data for legal operations requires economical, eco-friendly, and sensitive new materials. Here, a new composition of intense red-emitting Eu3+ and Y3+ co-doped SrTiO3 perovskites nanophosphor synthesized using a modified solgel-assisted combustion technique has been reported. To explore the structural and optical features of the nanophosphors the samples are characterized by various techniques. The powder XRD pattern reveals that the approximate crystallite size is 30 nm, which is consistent with TEM. It is found that with the mid- and near- ultraviolet light excitation, Eu3+ and Y3+ co-doped SrTiO3 nanophosphor displays a strong red emission at 618 nm for optimal concentrations (3 mol% Eu). The CIE (0.656, 0.344), color purity 95 %, CRI 98 %, and CCT values 2435 K, which is less than 5000 K reveals that the Eu3+ and Y3+ co-doped SrTiO3 phosphor was highly useful for the fabrication of warm LED and display device applications. Further, the optimized phosphor was tested (under UV light of 254 nm) for the visualization of LFP and security ink on various material surfaces. The results demonstrated that it provides an effective method for visualizing ridge patterns, offering a promising approach for applications in these areas. Based on the findings, Eu3+ and Y3+ co-doped SrTiO3 show potential for various optoelectronic applications, including WLEDs, LFP detection, security inks, and LEDs.
引用
收藏
页数:12
相关论文
共 64 条
[1]   RAMAN-SPECTRA OF STRONTIUM-TITANATE [J].
BALACHANDRAN, U ;
EROR, NG .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1982, 65 (04) :C54-C56
[2]   Photoluminescence studies of Eu3+ activated SrTiO3 nanophosphor prepared by solution combustion approach [J].
Bhagya, N. P. ;
Prashanth, P. A. ;
Krishna, R. Hari ;
Nagabhushana, B. M. ;
Raveendra, R. S. .
OPTIK, 2017, 145 :678-687
[3]   Structural, optical and cathodoluminescence characteristics of undoped and tin-doped ZnO thin films prepared by spray pyrolysis [J].
Bougrine, A ;
El Hichou, A ;
Addou, M ;
Ebothé, J ;
Kachouane, A ;
Troyon, M .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 80 (02) :438-445
[4]   The energy transfer of Bi3+ → Eu3+ and Bi3+ → Tb3+ in YBO3 host to produce light [J].
Chen, Lei ;
Jiang, Yang ;
Yang, Yunguang ;
Huang, Jian ;
Shi, Junyan ;
Chen, Shifu .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2009, 42 (21)
[5]   The standard and anomalous crystal-field spectra of Eu3+ [J].
Chen, XY ;
Liu, GK .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (02) :419-428
[6]   Effect of excitation wavelength and europium doping on the optical properties of nanoscale zinc oxide [J].
Choudhary, Ishan ;
Shukla, Ravi ;
Sharma, Arvind ;
Raina, K. K. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2020, 31 (22) :20033-20042
[7]   Long-range and short-range structures of cube-like shape SrTiO3 powders: microwave-assisted hydrothermal synthesis and photocatalytic activity [J].
da Silva, Luis F. ;
Avansi, Waldir, Jr. ;
Andres, Juan ;
Ribeiro, Caue ;
Moreira, Mario L. ;
Longo, Elson ;
Mastelaro, Valmor R. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (29) :12386-12393
[8]   Effective fingerprint recognition technique using doped yttrium aluminate nano phosphor material [J].
Darshan, G. P. ;
Premkumar, H. B. ;
Nagabhushana, H. ;
Sharma, S. C. ;
Prashanth, S. C. ;
Prasad, B. Daruka .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 464 :206-218
[9]   Large-scale controlled bio-inspired fabrication of 3D CeO2:Eu3+ hierarchical structures for evaluation of highly sensitive visualization of latent fingerprints [J].
Deepthi, N. H. ;
Darshan, G. P. ;
Basavaraj, R. B. ;
Prasad, B. Daruka ;
Nagabhushana, H. .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 255 :3127-3147
[10]   Significantly improved energy storage properties of sol-gel derived Mn-modified SrTiO3 thin films [J].
Diao, Chunli ;
Li, Hui ;
Yang, Yi ;
Hao, Hua ;
Yao, Zhonghua ;
Liu, Hanxing .
CERAMICS INTERNATIONAL, 2019, 45 (09) :11784-11791