Density, isothermal compressibility, isobaric thermal expansion, and related excess properties of mixtures of 2-(2-ethoxyethoxy)ethanol+2-propanol at temperatures from 293.15 K to 353.15 K and pressures up to 70 MPa: Measurements, correlation, and PC-SAFT modeling

被引:0
|
作者
Lifi, Mohamed [1 ,2 ]
Bazile, Jean-Patrick [2 ]
Daridon, Jean-Luc [2 ]
Montero, Eduardo A. [3 ]
Aguilar, Fernando [3 ]
Munoz-Rujas, Natalia [3 ]
机构
[1] Univ Burgos, Fac Sci, Dept Math & Comp, E-09003 Burgos, Spain
[2] Univ Pau & Pays Adour, CNRS, LFCR, E2S UPPA, F-64000 Pau, France
[3] Univ Burgos, Escuela Politecn Super, Dept Ingn Electromecan, E-09006 Burgos, Spain
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2025年 / 206卷
关键词
Oxygenated compounds; Density; Tait-like correlation; Isothermal compressibility; Isobaric thermal expansion; PC-SAFT modeling; VIBRATING TUBE DENSIMETER; GLYCOL MONOETHYL ETHER; PERTURBED-CHAIN SAFT; BINARY-MIXTURES; LIQUID DENSITY; VOLUMETRIC PROPERTIES; OXYGENATED ADDITIVES; THERMODYNAMIC PROPERTIES; REFRACTIVE-INDEXES; PLUS PROPAN-1-OL;
D O I
10.1016/j.jct.2025.107476
中图分类号
O414.1 [热力学];
学科分类号
摘要
High-temperature and high-pressure density data for the binary mixtures x 2-(2-ethoxyethoxy)ethanol + (1-x) 2propanol are presented in this work, covering temperatures from 293.15 to 353.15 K and at pressures from 0.1 to 70 MPa. The experimental density data were generated using a vibrating tube densimeter with an uncertainty of 0.5 kg/m3. Experimental density data was fitted by using the Tait-like equation, yielding low standard deviations. Derivative properties such as excess molar volumes, isothermal compressibilities, excess isothermal compressibilities, and isobaric thermal expansions were calculated from the obtained density data. Additionally, the experimental measurements were modeled using PC-SAFT equation of state. The intermolecular interactions, as reflected in the derivative properties for each binary mixture, are thoroughly discussed.
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页数:16
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