Crystal structure and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromophenyl)-1,2,3,4-tetrahydroquinolin-4-yl]pyrrolidin-2-one

被引：0

作者：

Pronina, Anastasia A. ^{[1
]}

Kutasevich, Alexandra G. ^{[1
]}

Grigoriev, Mikhail S. ^{[2
]}

Hasanov, Khudayar I. ^{[3
,4
]}

Sadikhova, Nurlana D. ^{[5
]}

Javadzade, Tahir A. ^{[6
]}

Akkurt, Mehmet ^{[7
]}

Bhattarai, Ajaya ^{[8
]}

机构：

[1] RUDN Univ, 6 Miklukho Maklaya St, Moscow 117198, Russia

[2] Russian Acad Sci, Frumkin Inst Phys Chem & Elect, Leninskiy Prospect 31-4, Moscow 119071, Russia

[3] Western Caspian Univ, Istiqlaliyyat St 31,AZ1001, Baku, Azerbaijan

[4] Azerbaijan Med Univ, Sci Res Ctr SRC, A Kasumzade St 14 AZ 1022, Baku, Azerbaijan

[5] Baku State Univ, Dept Chem, Z Xalilov Str 23,Az 1148, Baku, Azerbaijan

[6] Khazar Univ, Dept Chem & Chem Engn, Mahsati St 41,AZ 1096, Baku, Azerbaijan

[7] Erciyes Univ, Dept Phys, Fac Sci, Kayseri 38039, Turkiye

[8] Tribhuvan Univ, MMAMC, Dept Chem, Biratnagar, Nepal

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2024年 / 80卷

关键词：

crystal structure; hydrogen bonds; the Povarov method; tetrahydroquinoline; Hirshfeld surface analysis;

D O I：

10.1107/S2056989024008144

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

This study presents the synthesis, characterization and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromophenyl)-1,2,3,4-tetrahydroquinolin-4-yl]pyrrolidin-2-one, C19H18Br2N2O. In the title compound, the pyrrolidine ring adopts a distorted envelope configuration. In the crystal, molecules are linked by intermolecular N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot Br hydrogen bonds, forming a three-dimensional network. In addition, pairs of molecules along the c axis are connected by C-H center dot center dot center dot pi interactions. According to a Hirshfeld surface study, H center dot center dot center dot H (36.9%), Br center dot center dot center dot H/H center dot center dot center dot Br (28.2%) and C center dot center dot center dot H/H center dot center dot center dot C (24.3%) interactions are the most significant contributors to the crystal packing.

引用

页码：967 / +

页数：11

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