Reaction mechanism with indano[60]fullerene bromide for evaporable fullerene derivatives

被引：0

作者：

Amada, Hirofumi ^{[1
]}

Zhai, Yong-Chang ^{[1
]}

Yamanaka, Koki ^{[1
]}

Shui, Qing-Jun ^{[1
]}

Oyama, Kin-ichi ^{[2
]}

Miwa, Kazuhira ^{[1
]}

Lin, Hao-Sheng ^{[1
]}

Matsuo, Yutaka ^{[1
,3
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Chem Syst Engn, Furo Cho,Chikusa Ku, Nagoya 4648603, Japan

[2] Nagoya Univ, Res Ctr Mat Sci, Chem Instrumentat Facil, Furo Cho,Chikusa Ku, Nagoya 4648602, Japan

[3] Nagoya Univ, Inst Mat Innovat, Inst Innovat Future Soc, Furo Cho,Chikusa Ku, Nagoya 4648601, Japan

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 08期

基金：

日本学术振兴会;

关键词：

INHIBITION; POLYMER;

D O I：

10.1039/d4cc05600k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Indano[60]fullerene bromide was isolated as a key intermediate in the synthesis of indano[60]fullerene ketone, an evaporable fullerene derivative. Based on the identified reaction mechanism, aqueous hydrobromic acid was used to achieve reproducible and high-yielding reactions. A scalable one-pot reaction from aryl[60]fullerenyl dimers to indano[60]fullerene ketone was also demonstrated.

引用

页码：1665 / 1668

页数：4

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