Supramolecular Chemistry: An Enabling Tool for Asymmetric Catalysis

被引:0
作者
Cunningham, Laura [1 ]
机构
[1] Univ Galway, Sch Biol & Chem Sci, Galway, Ireland
关键词
asymmetric catalysis; supramolecular chemistry; macrocycle; metal-organic assemblies; host-guest systems; mechanically interlocked molecules; micelles; METAL-ORGANIC FRAMEWORKS; ROOM-TEMPERATURE; DNA; LIGAND; COMPLEXES; ORGANOCATALYSIS; CALIXARENES; SELECTIVITY; DESIGN; WATER;
D O I
10.1055/a-2513-2141
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Asymmetric synthesis and supramolecular chemistry are cornerstones of modern organic chemistry. The combination of both fields to develop new approaches to enantioselective catalysis has gained considerable momentum in recent years. Herein, we highlight some of the advantages offered by various supramolecular architectures over conventional chiral catalysts and reflect on obstacles that currently limit widespread use of supramolecular tools in asymmetric synthesis. 1 Introduction 2 Discussion 2.1 Macrocycles 2.2 Surfactants 2.3 Metal-Organic Cages and Frameworks 2.4 Covalent Organic Frameworks 2.5 DNA 2.6 Mechanically Interlocked Molecules 3 Summary and Outlook
引用
收藏
页码:1189 / 1200
页数:12
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