Photocatalytic Degradation of Sulfamethoxazole by Cd/Er-Doped Bi2MoO6

被引:2
作者
Yang, Nengxun [1 ]
Niu, Yixuan [1 ]
Zhang, Bohang [1 ]
Zhang, Fuchun [1 ]
机构
[1] Yanan Univ, Sch Phys & Elect Informat, Yanan 716000, Peoples R China
基金
中国国家自然科学基金;
关键词
photocatalysis; Bi2MoO6; hydrothermal method; co-doping; PERFORMANCE; ADSORPTION; REMOVAL; IRRADIATION; ACID;
D O I
10.3390/coatings14091112
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Bi2MoO6 (BMO) is a typical bismuth-based semiconductor material, and its unique Aurivillius structure provides a broad space for electron delocalization. In this study, a new type of bismuth molybdate Cd/Er-BMO photocatalytic material was prepared by co-doping Er3+ and Cd2+, and the performance of the photocatalytic degradation of sulfamethoxazole (SMZ) was systematically studied. The research results showed that the efficiency of SMZ degradation by Cd/Er-BMO was significantly improved after doping Er3+ and Cd2+ ions, reflecting the synergistic catalytic effect of Cd2+ and Er3+ co-doping. Cd/Er-BMO doped with 6% Cd had the highest degradation efficiency (93.89%) of SMZ under visible light irradiation. The material revealed excellent stability and reusability in repeated degradation experiments. In addition, 6% Cd/Er-BMO had a smaller particle size and a larger specific surface area, which is conducive to improving the generation efficiency of its photogenerated electron-hole pairs and reducing the recombination rate, significantly enhancing the photocatalysis of the material. This study not only provides an effective photocatalyst for degrading environmental pollutants such as SMZ, but also provides an important scientific basis and new ideas for the future development of efficient and stable photocatalytic materials.
引用
收藏
页数:15
相关论文
共 44 条
[1]   Effective CO2 photoreduction to methane over Bi2MoO6/ Ni, N co-doped TiO2 nano-photocatalyst [J].
Ahmadi, Maryam ;
Alavi, Seyed Mehdi ;
Larimi, Afsanehsadat .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 56 :1309-1323
[2]   Coupling physical adsorption and photocatalysis over CdS/UiO-66-NH2 for efficient removal of hydrogen sulfide [J].
Bai, Yaohui ;
Chen, Honghan ;
Cheng, Hao ;
Ding, Zhengxin ;
Yuan, Rusheng ;
Li, Zhaohui .
SEPARATION AND PURIFICATION TECHNOLOGY, 2024, 341
[3]   A review on capillary condensation in nanoporous media: Implications for hydrocarbon recovery from tight reservoirs [J].
Barsotti, Elizabeth ;
Tan, Sugata P. ;
Saraji, Soheil ;
Piri, Mohammad ;
Chen, Jin-Hong .
FUEL, 2016, 184 :344-361
[4]   Visible light induced hydrogen evolution over the heterosystem Bi2S3/TiO2 [J].
Brahimi, R. ;
Bessekhouad, Y. ;
Bouguelia, A. ;
Trari, M. .
CATALYSIS TODAY, 2007, 122 (1-2) :62-65
[5]   Enhanced photocatalytic activity of Te-doped Bi2MoO6 under visible light irradiation: Effective separation of photogenerated carriers resulted from inhomogeneous lattice distortion and improved electron capturing ability [J].
Chen, Shuguang ;
Li, Yuhan ;
Wu, Zixu ;
Wu, Baoxin ;
Li, Haibin ;
Li, Fujin .
JOURNAL OF SOLID STATE CHEMISTRY, 2017, 249 :124-130
[6]  
[戴佳佳 Dai Jiajia], 2023, [海洋与湖沼, Oceanologia et Limnologia Sinica], V54, P935
[7]   Cross-linked cellulose beads as an eco-friendly support for ZnO/SnO2/ carbon xerogel hybrid photocatalyst: Exploring the synergy between adsorption and photocatalysis under simulated sunlight [J].
de Moraes, Nicolas Perciani ;
Pereira, Renan Amarante ;
da Silva, Thiago Vieira Chicuta ;
da Silva, Bruno Henrique Baena ;
de Assis, Gabrielle Policarpo ;
Campos, Tiago Moreira Bastos ;
Thim, Gilmar Patrocinio ;
Lanza, Marcos Roberto de Vasconcelos ;
de Freitas, Larissa ;
Rodrigues, Liana Alvares .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2024, 254
[8]   Interpretation of Oxygen 1s X-ray Photoelectron Spectroscopy of ZnO [J].
Frankcombe, Terry J. J. ;
Liu, Yun .
CHEMISTRY OF MATERIALS, 2023, 35 (14) :5468-5474
[9]   Active sites modification and superior carriers separation synergistically boosted hydrogen production of Bi/Bi2MoO6/ZnIn2S4 non-noble metal S-scheme photocatalyst [J].
Geng, Liang ;
Li, Wenjun ;
Liu, Xintong ;
Li, Xinyang ;
Fan, Hongxia ;
Qiu, Hong ;
Ma, Xiaohui ;
Dong, Mei .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2023, 629 :723-732
[10]  
Gopal V., 2024, Catal. Commun., V187