Crystal Growth and Characterization of an Efficient Nonlinear Optical Material: γ-Glycine Crystal

被引:0
作者
Juliana, S. Gracelin [1 ]
Sathishkumar, P. [2 ,3 ]
Durai, S. C. Vella [2 ,3 ]
机构
[1] Nazareth Margoschis Coll, Dept Phys, Nazareth 628617, Tamilnadu, India
[2] Sri Paramakalyani Coll, PG & Res Dept Phys, Tenkasi 627412, Tamilnadu, India
[3] Manonmaniam Sundaranar Univ, Tirunelveli 627012, Tamilnadu, India
关键词
Gamma-glycine; Dielectrics; Transmittance; Hardness; Extinction coefficient; SINGLE-CRYSTALS; CRYSTALLIZATION; NUCLEATION;
D O I
10.56042/ijpap.v62i12.9843
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In an aqueous solution of ferrous chloride, gamma - Glycine Crystal (gamma-GC), an efficient nonlinear optical (NLO) material, was created. AR grade glycine and ferrous chloride in a molar ratio of 1: 0.5 were employed to grow the title sample. The lattice properties of gamma-GC were determined using a single crystal X-ray diffraction method. High transmittance in the visible area and a UV-visible spectrum make gamma-GC excellent for optical applications. Using a Nd:YAG laser, the produced crystal's LDT value was ascertained. The crystal's hardness was assessed using the Vickers test, and other mechanical properties were determined. The electrical properties of gamma-GC were examined by measuring the dielectric constant and dielectric loss at various frequencies, and temperatures. Using TG/DTA tests to gauge the sample's thermal stability, the functional groups of the gamma-GC were identified by FTIR analysis. The material also underwent SHG and LDT testing.
引用
收藏
页码:1098 / 1105
页数:8
相关论文
共 36 条
[1]   The crystallization of glycine polymorphs from emulsions, microemulsions, and lamellar phases [J].
Allen, K ;
Davey, RJ ;
Ferrari, E ;
Towler, C ;
Tiddy, GJ ;
Jones, MO ;
Pritchard, RG .
CRYSTAL GROWTH & DESIGN, 2002, 2 (06) :523-527
[2]   On the electrical and optical properties of CdS films thermally deposited by a modified source [J].
Ashour, A ;
ElKadry, N ;
Mahmoud, SA .
THIN SOLID FILMS, 1995, 269 (1-2) :117-120
[3]   Growth, structural, optical and thermal properties of γ-glycine crystal [J].
Balakrishnan, T. ;
Babu, R. Ramesh ;
Ramamurthi, K. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2008, 69 (04) :1114-1118
[4]   Bulk growth of (101) KDP crystal by Sankaranarayanan-Ramasamy method and its characterization [J].
Balamurugan, S. ;
Ramasamy, P. .
MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (01) :1-4
[5]   Polarised IR and Raman spectra of the γ-glycine single crystal [J].
Baran, J ;
Ratajczak, H .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 61 (07) :1611-1626
[6]   Effect of solvents on the growth morphology and physical characteristics of nonlinear optical γ-glycine crystals [J].
Bhat, MN ;
Dharmaprakash, SM .
JOURNAL OF CRYSTAL GROWTH, 2002, 242 (1-2) :245-252
[7]   Selective glycine polymorph crystallization by using microporous membranes [J].
Di Profio, Gianluca ;
Tucci, Selene ;
Curcio, Efrem ;
Drioli, Enrico .
CRYSTAL GROWTH & DESIGN, 2007, 7 (03) :526-530
[8]   Crystal growth and characterization of γ-glycine grown from potassium fluoride for photonic applications [J].
Dillip, G. R. ;
Raghavaiah, P. ;
Mallikarjuna, K. ;
Reddy, C. Madhukar ;
Bhagavannarayana, G. ;
Kumar, V. Ramesh ;
Raju, B. Deva Prasad .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 79 (05) :1123-1127
[9]   DEUTERATED L-ARGININE PHOSPHATE - A NEW EFFICIENT NONLINEAR CRYSTAL [J].
EIMERL, D ;
VELSKO, S ;
DAVIS, L ;
WANG, F ;
LOIACONO, G ;
KENNEDY, G .
IEEE JOURNAL OF QUANTUM ELECTRONICS, 1989, 25 (02) :179-193
[10]   Crystallization in polymorphic systems:: The solution-mediated transformation β to α glycine [J].
Ferrari, ES ;
Davey, RJ ;
Cross, WI ;
Gillon, AL ;
Towler, CS .
CRYSTAL GROWTH & DESIGN, 2003, 3 (01) :53-60