A journey into trifluoromethylchalcogenation: some reagents from Lyon

被引:0
作者
Billard, Thierry [1 ]
机构
[1] Univ Lyon 1, CNRS, UMR 5246, Inst Chem & Biochem ICBMS,CPE Lyon, 1 Rue Victor Grignard, F-69622 Lyon, France
关键词
Review article; Trifluoromethoxylation; Trifluoromethylthiolation; Trifluoromethylselenolation; Trifluo-romethanesulfenamide; DNTFB; TRIFLUOROMETHANESULFENAMIDE REAGENT; ELECTROPHILIC TRIFLUOROMETHYL; DIFLUOROMETHYL THIOETHERS; SUBSTITUENT CONSTANTS; UMPOLUNG REACTIVITY; TRIMETHYLSILANE; SULFIDES; 1ST; 2ND-GENERATION; RESONANCE;
D O I
10.5802/crchim.341
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of emerging fluorinated groups is an active field of research in recent years. In particular, the fusion of fluorinated moieties with chalcogens has attracted considerable interest. This has led to a strong demand for the development of new efficient reagents to perform various direct trifluoromethylchalcogenations. Herein, we present an overview of the results obtained in our laboratory in Lyon, which has actively contributed to this quest during the last 15 years.
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页数:11
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