Multi-residue analytical method development and dietary exposure risk assessment of 345 pesticides in mango by LC-Q-TOF/MS

被引:0
|
作者
Wu, Xingqiang [1 ]
Li, Jianxun [3 ]
Wei, Jing [2 ]
Tong, Kaixuan [1 ]
Xie, Yujie [1 ]
Chang, Qiaoying [1 ]
Yu, Xiaoxuan [1 ]
Li, Bei [2 ]
Lu, Meiling [4 ]
Fan, Chunlin [1 ]
Chen, Hui [1 ]
机构
[1] Chinese Acad Inspect & Quarantine, Key Lab Food Qual & Safety State Market Regulat, Beijing 100176, Peoples R China
[2] Hainan Inst Food Control, Key Lab Trop Fruits & Vegetables Qual & Safety Sta, Haikou 570314, Peoples R China
[3] Chinese Acad Agr Sci, Inst Food Sci & Technol, Beijing 100193, Peoples R China
[4] Agilent Technol China Ltd, Beijing 100102, Peoples R China
关键词
Mango; LC-Q-TOF/MS; QuEChERS; Pesticide residues; Risk assessment; VEGETABLES;
D O I
10.1016/j.foodcont.2024.111016
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Mango is attracting increasing global attention for its superior flavor and nutritional benefits. However, the use of pesticides has resulted in a threat to its quality, safety, and human health due to their inevitable residue. There is an urgent need for advanced technologies that can efficiently and sensitively analyze a wide range of pesticides. In this study, a high-throughput screening and quantification method for 345 pesticides in mango was established by applying a modified QuEChERS method combined with liquid chromatography-quadrupole-timeof-flight mass spectrometry (LC-Q-TOF/MS). A response surface methodology (RSM) optimized the critical parameters for extracting various pesticides in 1% acetic acid-acetonitrile (v/v) using MgSO4, PSA, C18, and GCB as the adsorbents. The proposed method was successfully validated and applied to the quantitative detection of pesticide residues in 73 mango samples from Hainan. The study found pesticide residues in 95.9% of mango samples, of which 3 samples had residue concentrations in excess of the Chinese maximum residue limit. A total of 24 pesticides were detected, with detection percentages ranging from 1.4% (Thiabendazole) to 41.1% (Pyraclostrobin). Considering the possible health risks related to pesticide residues, risk assessment of human exposure to pesticides via intake of mango was evaluated. The acute and chronic dietary exposure risks related to pesticide residues in mango were accepted. In conclusion, this study provides a powerful platform for monitoring multiple pesticides in mango. First, it can promote the rational use of pesticides, and second, it can help consumers to assess the risk of dietary exposure to pesticide residues.
引用
收藏
页数:9
相关论文
共 42 条
  • [21] Multi-residue monitoring and dietary risk assessment of 17 pesticides and 3 related metabolites in rice and rice flour from markets in China
    Jisheng Zhao
    Pengfei Li
    Jiye Hu
    Environmental Science and Pollution Research, 2024, 31 : 5275 - 5288
  • [22] Multi-residue monitoring and dietary risk assessment of 17 pesticides and 3 related metabolites in rice and rice flour from markets in China
    Zhao, Jisheng
    Li, Pengfei
    Hu, Jiye
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2024, 31 (04) : 5275 - 5288
  • [23] Analysis of 181 Pesticides with Multi-residue Method by LC-MS/MS and GC-MS/MS in Flowers, Leaves and Tree Trunks and the Results of Catalan Production from 2014 to 2021
    Sanchez Costa, Laia
    Pujol Boira, Judit
    Arago Iglesias, Miriam
    Rodriguez Martinez, Pilar
    Medina Sala, Mireia
    FOOD ANALYTICAL METHODS, 2023, 16 (02) : 239 - 251
  • [24] Multi-residue methods for pesticide analysis in food control - possibilities and limitations, Part 3: Variation of the BfR method for the universal application of the residue-determination with GC-MS-TOF and LC-MS-MS
    Hemmerling, Christlieb
    Augustyniak, Bettina
    Maye, Astrid
    Seidl, Gilda
    Warschewske, Guido
    DEUTSCHE LEBENSMITTEL-RUNDSCHAU, 2009, 105 (10) : 633 - 644
  • [25] Multi-residue Analysis Method for Analysis of Pharmaceuticals using Liquid Chromatography-Time of Flight/Mass Spectrometry (LC-TOF/MS) in Water Sample
    Al-Qaim, Fouad Fadhil
    Abdullah, Md Pauzi
    Othman, Mohamed Rozali
    2013 UKM FST POSTGRADUATE COLLOQUIUM, 2013, 1571 : 806 - 811
  • [26] Residue behavior and dietary risk assessment of six pesticides in pak choi using QuEChERS method coupled with UPLC-MS/MS
    Tang, Hongxia
    Ma, Lin
    Huang, Jiaqing
    Li, Yubo
    Liu, Zehui
    Meng, Dianying
    Wen, Guangyue
    Dong, Maofeng
    Wang, Weimin
    Zhao, Li
    ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2021, 213
  • [27] Persistence, decontamination and dietary risk assessment of propyrisulfuron residue in natural paddy field environment using QuEChERS@UPLC-Q-TOF-MS/MS
    Dong, Zemin
    Zhou, Rendan
    Bian, Chuanfei
    Li, Han
    Wang, Long
    Fu, Jinhua
    Xie, Guai
    Shi, Xianluo
    Li, Xianghong
    Li, Zhiyuan
    Li, Baotong
    MICROCHEMICAL JOURNAL, 2022, 181
  • [28] MULTI-RESIDUE ANALYSIS OF 405 PESTICIDES IN AGRICULTRAL CROPS IN MIDDLE GOVERNORATES OF JORDAN IN 2018 AND 2019 USING QuEChERS METHOD FOLLOWED BY LC-MS/MS AND GC-ECD
    Al-Antary, Tawfiq M.
    Alawi, Mahmoud A.
    Masaedeh, Maram
    Haddad, Nizar A.
    FRESENIUS ENVIRONMENTAL BULLETIN, 2020, 29 (04): : 2534 - 2539
  • [29] Fate of multi-residue insecticides and their metabolites in the process of vinification: Analytical method validation, dissipation kinetics, processing factor, and risk assessment
    Shabeer, T. P. Ahammed
    Hingmire, Sandip
    Taynath, Bharat
    Deshmukh, Umakant
    Somkuwar, Ramhari
    Sharma, Ajay Kumar
    ENVIRONMENTAL POLLUTION, 2024, 352
  • [30] Development of high-throughput multi-residue method for non-steroidal anti-inflammatory drugs monitoring in swine muscle by LC-MS/MS
    Castilhos, Tamara S.
    Barreto, Fabiano
    Meneghini, Leonardo
    Bergold, Ana Maria
    FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT, 2016, 33 (07): : 1166 - 1174