Investigation of Potential-Induced Degradation in Perovskite Solar Cells under Inert Conditions

被引:0
作者
Breugelmans, Robbe [1 ,2 ,3 ]
Lammar, Stijn [1 ,2 ,3 ,4 ]
Aguirre, Aranzazu [1 ,2 ,3 ]
Aernouts, Tom [1 ,2 ,3 ]
Vermang, Bart [1 ,2 ,3 ]
Daenen, Michael [1 ,2 ,3 ]
机构
[1] Hasselt Univ, Imo Imomec, Hasselt, Belgium
[2] Imec, Imo Imomec, Genk, Belgium
[3] EnergyVille, Imo Imomec, Genk, Belgium
[4] Katholieke Univ Leuven, Dept Elect Engn ESAT, Leuven, Belgium
关键词
PL; potential-induced degradation; sodium ions; ToF-SIMS; XRD;
D O I
10.1002/solr.202400923
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology due to their remarkable efficiency advancements. However, their commercialization is hindered by stability challenges, including sensitivity to environmental conditions and a critical degradation mechanism known as potential-induced degradation (PID). PID can significantly impair PSC performance within hours under operational conditions. This study investigates PID in 48 triple-cation p-i-n PSCs over 313 h in an inert environment, excluding additional stressors like moisture and oxygen. The PID-stressed devices degraded to 79% of their initial efficiency, primarily driven by losses in short-circuit current density. Time-of-flight secondary ion mass spectroscopy revealed sodium ion migration from soda-lime glass substrates into the perovskite layer. Interestingly, photoluminescence and X-ray diffraction analyses detected no measurable differences between PID-stressed and reference devices, contradicting prior literature that associates PID with perovskite segregation and decomposition. These findings challenge the conventional understanding of PID, suggesting that environmental factors such as oxygen and moisture might exacerbate degradation effects. This work provides critical insights into the intrinsic mechanisms of PID under controlled conditions and highlights the need for further research into the interplay between PID and environmental stressors to guide the development of more stable PSC technologies.
引用
收藏
页数:8
相关论文
共 29 条
[1]   Perovskite Solar Cells: A Review of the Latest Advances in Materials, Fabrication Techniques, and Stability Enhancement Strategies [J].
Afre, Rakesh A. ;
Pugliese, Diego .
MICROMACHINES, 2024, 15 (02)
[2]   Understanding Degradation Mechanisms and Improving Stability of Perovskite Photovoltaics [J].
Boyd, Caleb C. ;
Cheacharoen, Rongrong ;
Leijtens, Tomas ;
McGehee, Michael D. .
CHEMICAL REVIEWS, 2019, 119 (05) :3418-3451
[3]   Are Perovskite Solar Cell Potential-Induced Degradation Proof? [J].
Brecl, Kristijan ;
Jost, Marko ;
Bokalic, Matevz ;
Ekar, Jernej ;
Kovac, Janez ;
Topic, Marko .
SOLAR RRL, 2022, 6 (02)
[4]  
Breugelmans R., 2025, MRS BULL, V12, P1
[5]   Method to Study Potential-Induced Degradation of Perovskite Solar Cells and Modules in an Inert Environment [J].
Breugelmans, Robbe ;
Lammar, Stijn ;
Aguirre, Aranzazu ;
Aernouts, Tom ;
Vermang, Bart ;
Daenen, Michael .
SOLAR RRL, 2024, 8 (11)
[6]   Recent Advances in UV-Cured Encapsulation for Stable and Durable Perovskite Solar Cell Devices [J].
Cao, Mengyu ;
Ji, Wenxi ;
Chao, Cong ;
Li, Ji ;
Dai, Fei ;
Fan, Xianfeng .
POLYMERS, 2023, 15 (19)
[7]   Potential-Induced Degradation and Recovery of Perovskite Solar Cells [J].
Carolus, Jorne ;
Merckx, Tamara ;
Purohit, Zeel ;
Tripathi, Brijesh ;
Boyen, Hans-Gerd ;
Aernouts, Tom ;
De Ceuninck, Ward ;
Conings, Bert ;
Daenen, Michael .
SOLAR RRL, 2019, 3 (10)
[8]   The Promise and Challenges of Inverted Perovskite Solar Cells [J].
Chen, Peng ;
Xiao, Yun ;
Li, Shunde ;
Jia, Xiaohan ;
Luo, Deying ;
Zhang, Wei ;
Snaith, Henry J. ;
Gong, Qihuang ;
Zhu, Rui .
CHEMICAL REVIEWS, 2024, 124 (19) :10623-10700
[9]   Roadmap on commercialization of metal halide perovskite photovoltaics [J].
Feng, Shien-Ping ;
Cheng, Yuanhang ;
Yip, Hin-Lap ;
Zhong, Yufei ;
Fong, Patrick W. K. ;
Li, Gang ;
Ng, Annie ;
Chen, Cong ;
Castriotta, Luigi Angelo ;
Matteocci, Fabio ;
Vesce, Luigi ;
Saranin, Danila ;
Di Carlo, Aldo ;
Wang, Puqun ;
Ho, Jian Wei ;
Hou, Yi ;
Lin, Fen ;
Aberle, Armin G. ;
Song, Zhaoning ;
Yan, Yanfa ;
Chen, Xu ;
Yang, Yang ;
Syed, Ali Asgher ;
Ahmad, Ishaq ;
Leung, Tiklun ;
Wang, Yantao ;
Lin, JingYang ;
Ng, Alan Man Ching ;
Li, Yin ;
Ebadi, Firouzeh ;
Tress, Wolfgang ;
Richardson, Giles ;
Ge, Chuangye ;
Hu, Hanlin ;
Karimipour, Masoud ;
Baumann, Fanny ;
Tabah, Kenedy ;
Pereyra, Carlos ;
Raga, Sonia R. ;
Xie, Haibing ;
Lira-Cantu, Monica ;
Khenkin, Mark, V ;
Visoly-Fisher, Iris ;
Katz, Eugene A. ;
Vaynzof, Yana ;
Vidal, Rosario ;
Yu, Guicheng ;
Lin, Haoran ;
Weng, Shuchen ;
Wang, Shifeng .
JOURNAL OF PHYSICS-MATERIALS, 2023, 6 (03)
[10]  
Gholipour S., 2020, CHARACTERIZATION TEC, P1, DOI DOI 10.1016/B978-0-12-814727-6.00001-3