Recent Advances in Smart Sensing Based on Excited-State Intramolecular Proton-Transfer (ESIPT)-Inspired Emitters

被引：2
作者：
Li, Jing [1 ]
Xu, Bao-Sen [1 ]
Zhao, Le-Le [1 ]
Yi, Shao-Zhe [2 ]
Li, Bao-Ning [1 ,2 ]
机构：
[1] Yulin Univ, Sch Chem & Chem Engn, Yulin 719000, Peoples R China
[2] Sun Yat Sen Univ, Lehn Inst Funct Mat, Sch Chem, Guangzhou 510275, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 14卷 / 02期
关键词：
Excited State Intramolecular Proton Transfer (ESIPT); Emission-Regulation; Chemosensor; RATIOMETRIC FLUORESCENT-PROBE; TRANSFER ESIPT; ALKALINE-PHOSPHATASE; SELECTIVE DETECTION; HYDROGEN-PEROXIDE; EMISSION; RECOGNITION; MECHANISM; CYSTEINE; CU2+;
D O I：
10.1002/ajoc.202400572
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The optical materials based on excited state intramolecular proton transfer (ESIPT) have garnered significant attention due to their unique photophysical properties and applications in sensors and imaging agents (probes). These materials exhibit an intrinsic four-level photocycle scheme through the enol (E)-keto (K) phototautomerization process, resulting in a large Stokes shift, environmental sensitivity, and potential for ratiometric sensing. This review primarily focuses on elucidating the luminescence mechanism and structure-property relationships of recent ESIPT molecules, as well as exploring the sensing applications of phosphorescent functional materials.
引用
收藏
页数：27
相关论文
共 50 条
  • [31] Mechanism of Excited-State Intramolecular Proton Transfer for 1,2-Dihydroxyanthraquinone: Effect of Water on the ESIPT
    Peng, Yajing
    Ye, Yuqing
    Xiu, Xianming
    Sunt, Shuang
    JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 121 (30) : 5625 - 5634
  • [32] The indanone N-H type excited-state intramolecular proton transfer (ESIPT); the observation of a mechanically induced ESIPT reaction
    You, Jhu-Jyun
    Lin, Yan-Ding
    Hsu, Chao-Hsien
    Hu, Jiun-Wei
    Tsai, Ying-Yi
    Qu, Hao-Ting
    Chen, Kew-Yu
    Chou, Pi-Tai
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2024, 26 (40) : 25767 - 25771
  • [33] Benzothiazole-Based AIEgen with Tunable Excited-State Intramolecular Proton Transfer and Restricted Intramolecular Rotation Processes for Highly Sensitive Physiological pH Sensing
    Li, Kai
    Feng, Qi
    Niu, Guangle
    Zhang, Weijie
    Li, Yuanyuan
    Kang, Miaomiao
    Xu, Kui
    He, Juan
    Hou, Hongwei
    Tang, Ben Zhong
    ACS SENSORS, 2018, 3 (05): : 920 - 928
  • [34] Interplay of Dual-Proton Transfer Relay to Achieve Full-Color Panel Luminescence in Excited-State Intramolecular Proton Transfer (ESIPT) Fluorophores
    Yi, Shao-Zhe
    Li, Bao-Ning
    Fu, Peng-Yan
    Pan, Mei
    Su, Cheng-Yong
    ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (02) : 3172 - 3181
  • [35] A highly selective ratiometric detection of F- based on excited-state intramolecular proton-transfer (imidazole) materials
    Dhanunjayarao, Kunchala
    Mukundam, Vanga
    Venkatasubbaiah, Krishnan
    JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (40) : 8599 - 8606
  • [36] Computational Insights into Sensing Mechanism for Al3+in a New Acylhydrazone Fluorescent Probe Based on Excited-State Intramolecular Proton Transfer (ESIPT) and Twisted Intramolecular Charge Transfer (TICT)
    Sun, Guotao
    Fang, Hua
    JOURNAL OF PHYSICAL CHEMISTRY A, 2023, 127 (08) : 1857 - 1865
  • [37] Self-absorption-free excited-state intramolecular proton transfer (ESIPT) emitters for high brightness and luminous efficiency organic fluorescent electroluminescent devices
    Kumsampao, Jakkapan
    Chaiwai, Chaiyon
    Sukpattanacharoen, Chattarika
    Chawanpunyawat, Thanyarat
    Nalaoh, Phattananawee
    Chasing, Pongsakorn
    Kungwan, Nawee
    Sudyoadsuk, Taweesak
    Promarak, Vinich
    MATERIALS CHEMISTRY FRONTIERS, 2021, 5 (16) : 6212 - 6225
  • [38] Excited-state intramolecular proton transfer in the kinetic-control regime
    Liu, Zong-Ying
    Hu, Jiun-Wei
    Huang, Teng-Hsing
    Chen, Kew-Yu
    Chou, Pi-Tai
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (39) : 22271 - 22278
  • [39] Nitrile-substituted 2-(oxazolinyl)-phenols: minimalistic excited-state intramolecular proton transfer (ESIPT)-based fluorophores
    Goebel, Dominik
    Duvinage, Daniel
    Stauch, Tim
    Nachtsheim, Boris J.
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (27) : 9213 - 9225
  • [40] Theoretical insights into excited-state hydrogen bonding effects and intramolecular proton transfer (ESIPT) mechanism for BTS system
    Wang, Jiemin
    Liu, Qiang
    Yang, Dapeng
    SCIENTIFIC REPORTS, 2020, 10 (01)
12345