Spatiotemporal variability of groundwater chemistry, source identification and health risks in the southern Chinese Loess Plateau

Groundwater pollution of the loess plateau regions has become a global concern due to its vulnerability to natural and anthropogenic influences. In this study, 146 water samples were investigated to identify the spatiotemporal variability in groundwater chemistry, pollution sources and nitrate health risks in two interconnected river basins of a typical loess region. The results showed that except for bicarbonate, spatiotemporal variability of hydrochemical components in Malian River Basin (ML) was generally greater than that in Upper Jinghe River basin (JH-U) due to the hydrogeological conditions, and the hydrochemical facies in two river basins transformed from SO4 center dot Cl and Cl center dot SO4 types to HCO3 and HCO3 center dot SO4 types. The results of integrated-weight quality index (IWQI) showed that 77.8 % (1970s), 33.3 % (2004), 34.3 % (2015) of samples in ML exceeded the standard limits of Class IV groundwater quality, displaying a high pollution level with an improvement trend, while groundwater quality in JH-U indicated a very low pollution level with a deterioration trend. The geogenic source was identified as a main factor affecting groundwater quality, with contributions of 59.2 % and 48.7 % in JH-U and ML (2015), respectively. The anthropogenic sources including agricultural activities (20.7 % and 21.8 % in JH-U and ML) and coal mining activities (20.1 % and 29.5 % in JH-U and ML) also played a role in affecting groundwater quality. The nitrate health risk assessment demonstrated that 39.1 % and 20.3 % of groundwater samples (2015) significantly exceeded the standard threshold (Hazard Index = 1), implying a higher health risk to children than adults, and the nitrate health risk in ML was obviously greater than that in JHU. This study provides novel insight into the spatiotemporal variability in groundwater chemistry, quality and health risk in loess regions under the influence of geogenic and anthropogenic factors.