Dry Magnetic Separation and the Leaching Behaviour of Aluminium, Iron, Titanium, and Selected Rare Earth Elements (REEs) from Coal Fly Ash

Coal fly ash (CFA) is a commercially viable source of alumina comparable to traditional bauxite deposits. Due to its high silica content and alumina in the refractory mullite phase, the most suitable processing technique is the sinter-H2SO4 leach process. However, this process is energy-intensive, has low selectivity for Al, and generates a secondary solid waste residue. To develop a sustainable process that is economically attractive, Al can be extracted with REEs, Ti, and Fe as saleable products, while secondary solid waste is regenerated for further applications to achieve high-value and high-volume utilisation of CFA. This study focused on the potential extraction of selected REEs (Ce, La, Nd, Y, and Sc), Al, Ti, and Fe, using dry magnetic separation and the sinter-H2SO4 leach process. XRD analysis showed that CFA is predominantly amorphous with crystalline mullite, quartz, and magnetite/hematite. Further analysis using SEM-EDS and TIMA showed Al-Si-rich grains as the predominant phase, with discrete REE-bearing grains (phosphates and silicates) and Fe-oxide (magnetite/hematite) grains. Traces of REEs, Ti, Ca, Si, and Fe were also found in the Al-Si-rich grains. Discrete Fe-oxide was recovered using dry magnetic separation, and up to 65.9% Fe was recovered at 1.05 T as the magnetic fraction (MF). The non-magnetic fraction (non-MF) containing quartz, mullite, and amorphous phase was further processed for preliminary leaching studies. The leaching behaviour of Al, Ti, Fe, and the selected REEs was investigated using the direct H2SO4 and sinter-H2SO4 leaching processes. The maximum extraction efficiency was observed using the sinter-H2SO4 leach process at 6 M H2SO4, a 1:5 solid-to-liquid ratio, 70 degrees C, and a residence time of 10 h, yielding 77.9% Al, 62.1% Fe, 52.3% Ti, and 56.7% Sc extractions. The extraction efficiencies for Ce, La, Nd, and Y were relatively lower at 23.2%, 27.6%, 11.3%, and 11.2%, respectively. Overall, the results demonstrate that the extraction of REEs using the sinter-H2SO4 leach process is strongly influenced by the complex CFA phase composition and the possible formation of insoluble calcium sulphates. Appreciable extraction of Al, Fe, Ti, and Sc was also observed, suggesting a potential two-step leaching process for the extraction of REEs as a feasible option for the industrial recovery of multiple saleable products.