Hardening mechanism and plastic deformation behavior in super-hard AlCrNbSiTiN high-entropy nitride nanocomposite coatings

被引:3
作者
Zhang, Xiangyu [1 ]
Zeng, Zhong [1 ]
Zeng, Xiaomei [1 ]
Pelenovich, Vasiliy [2 ]
Wan, Qiang [3 ]
Pogrebnjak, Alexander [4 ,5 ]
Xue, Longjian [1 ]
Chen, Yanming [1 ]
Yang, Bing [1 ,6 ]
机构
[1] Wuhan Univ, Sch Power & Mech Engn, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Inst Technol Sci, Wuhan 430072, Peoples R China
[3] Huazhong Agr Univ, Coll Engn, Wuhan, Peoples R China
[4] Sumy State Univ, Inst Nanoelect & Surface Modificat, Sumy, Ukraine
[5] Slovak Univ Technol Bratislava, Inst Mat Sci & Technol, Trnava, Slovakia
[6] Wuhan Univ, Shenzhen Res Inst, Shenzhen, Peoples R China
来源
MATERIALS RESEARCH LETTERS | 2025年 / 13卷 / 02期
基金
中国国家自然科学基金;
关键词
High-entropy nitride coatings; nanocomposite structure; mechanical properties; hardening mechanism; plastic deformation behavior; TITANIUM ALUMINUM NITRIDE; MICROSTRUCTURE; DEPOSITION; FILMS; TEMPERATURE; TRIBOLOGY; ALLOYS; TIN;
D O I
10.1080/21663831.2024.2425167
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The rapid development of industrial applications places severe demands on the mechanical properties of protective coatings. Unraveling the hardening mechanism and deformation behavior is essential for the design of advanced hard coatings. In this paper, a novel AlCrNbSiTiN high-entropy nitride (HEN) coating with an extremely low wear rate of 6.3 x 10-7 mm3 N-1 m-1 and super-hardness of 46 GPa was deposited. The variation of ion-bombardment energy induces the transformation of the nanocomposite structure and hardening mechanism. The plastic deformation behavior was revealed using Ex situ TEM observation and the MeN-Si3N4 nanocomposite structure is a critical contributor to the outstanding mechanical properties and resistance to deformation.
引用
收藏
页码:103 / 112
页数:10
相关论文
共 48 条
[1]   Interdependence between stress, preferred orientation, and surface morphology of nanocrystalline TiN thin films deposited by dual ion beam sputtering [J].
Abadias, G. ;
Tse, Y. Y. ;
Guerin, Ph. ;
Pelosin, V. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (11)
[2]   In situ stress evolution during magnetron sputtering of transition metal nitride thin films [J].
Abadias, G. ;
Guerin, Ph. .
APPLIED PHYSICS LETTERS, 2008, 93 (11)
[3]   Influence of bias variation on residual stress and texture in TiAIN PVD coatings [J].
Ahlgren, M ;
Blomqvist, H .
SURFACE & COATINGS TECHNOLOGY, 2005, 200 (1-4) :157-160
[4]   High-entropy ceramics: Review of principles, production and applications [J].
Akrami, Saeid ;
Edalati, Parisa ;
Fuji, Masayoshi ;
Edalati, Kaveh .
MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2021, 146
[5]   Unprecedented thermal stability of inherently metastable titanium aluminum nitride by point defect engineering [J].
Baben, Moritz to ;
Hans, Marcus ;
Primetzhofer, Daniel ;
Evertz, Simon ;
Ruess, Holger ;
Schneider, Jochen M. .
MATERIALS RESEARCH LETTERS, 2017, 5 (03) :158-169
[6]   Microstructural development in equiatomic multicomponent alloys [J].
Cantor, B ;
Chang, ITH ;
Knight, P ;
Vincent, AJB .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 375 :213-218
[7]   Influence of substrate bias and temperature on the crystallization of metallic NbTaTiVZr high-entropy alloy thin films [J].
Cemin, Felipe ;
de Mello, Saron R. S. ;
Figueroa, Carlos A. ;
Alvarez, Fernando .
SURFACE & COATINGS TECHNOLOGY, 2021, 421
[8]   Effect of interlayer design on the mechanical properties of AlTiCrN and multilayered AlTiCrN/TiSiN hard coatings [J].
Chang, Yin-Yu ;
Yang, Yu-Ju ;
Weng, Shi-Yao .
SURFACE & COATINGS TECHNOLOGY, 2020, 389
[9]   Commentary on using H/E and H3/E2 as proxies for fracture toughness of hard coatings [J].
Chen, Xinjie ;
Du, Yao ;
Chung, Yip-Wah .
THIN SOLID FILMS, 2019, 688
[10]   Effect of substrate bias on structure and properties of (AlTiCrZrNb)N high-entropy alloy nitride coatings through arc ion plating [J].
Cheng, Chi ;
Li, Haiqing ;
Zhang, Cheng ;
Guo, Chaoqian ;
Li, Jianwei ;
Zhang, Haoqiang ;
Lin, Songsheng ;
Wang, Qimin .
SURFACE & COATINGS TECHNOLOGY, 2023, 467