Source and Ecological Risk Assessment of Potentially Toxic Metals in Urban Riverine Sediments Using Multivariate Analytical and Statistical Tools

Multivariate and statistical tool advancements help to assess potential pollution threats, their geochemical distribution, and the competition between natural and anthropogenic influences, particularly on sediment contamination with potentially toxic metals (PTMs). For this, riverine sediments from 25 locations along urban banksides of the River Ravi, Pakistan, were collected and analyzed to explore the distribution, pollution, ecological, and toxicity risk indices of PTMs like Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Sn, Sr, V, and Zn using Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES) technique. Additionally, techniques such as X-ray Diffraction (XRD) and Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy (SEM-EDS) were employed to investigate the mineralogical and morphological aspects. The results indicated that mean concentrations (mg kg-1) of Cd (2.37), Cr (128), Hg (16.6), Pb (26.6), and Sb (2.44) were significantly higher than reference values given for upper continental crust (UCC) and world soil average (WSA), posing potential threats. Furthermore, the geochemical pollution indices showed that sediments were moderately polluted with Cd (Igeo = 2.37, EF = 12.1, and CF = 7.89) and extremely polluted with Hg (Igeo = 4.54, EF = 63.2, and CF = 41.41). Ecological and toxicity risks were calculated to be extremely high, using respective models, predominantly due to Hg (Eri = 1656 and ITRI = 91.6). SEM-EDS illustrated the small extent of anthropogenic particles having predominant concentrations of Zn, Fe, Pb, and Sr. Multivariate statistical analyses revealed significant associations between the concentrations of PTMs and the sampling locations, highlighting the anthropogenic contributions linked to local land-use characteristics. The present study concludes that River Ravi sediments exhibit moderate levels of Cd and extreme pollution by Hg, both of which contribute highly to extreme ecological and toxicity risks, influenced by both natural and anthropogenic contributions.