Enhanced Degradation of Norfloxacin Under Visible Light by S-Scheme Fe2O3/g-C3N4 Heterojunctions

被引:3
作者
Lu, Guang [1 ]
Li, Wei [2 ]
Li, Zheng [2 ]
Gu, Guizhou [3 ]
Han, Qiuju [3 ]
Liang, Jiling [1 ]
Chen, Zhen [4 ]
机构
[1] Liaoning Petrochem Univ, Sch Civil Engn, Fushun 113001, Peoples R China
[2] Liaoning Petrochem Univ, Sch Environm & Safety Engn, Fushun 113001, Peoples R China
[3] Liaoning Petrochem Univ, Sch Petrochem Engn, Fushun 113001, Peoples R China
[4] Shenyang Ligong Univ, Sch Environm & Chem Engn, Shenyang 110159, Peoples R China
基金
美国国家科学基金会;
关键词
Fe2O3; g-C3N4; heterojunction; photocatalytic degradation; NOR; PHOTOCATALYTIC ACTIVITY; FABRICATION; COMPOSITE;
D O I
10.3390/molecules29215212
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
S-scheme Fe2O3/g-C3N4 heterojunctions were successfully fabricated by the ultrasonic assistance method to remove norfloxacin (NOR) under visible light irradiation. The synthesized catalysts were well studied through various techniques. The obtained Fe2O3/g-C3N4 heterojunctions exhibited an optimal photocatalytic degradation of 94.7% for NOR, which was 1.67 and 1.28 times higher than using Fe2O3 and g-C3N4 alone, respectively. In addition, the kinetic constant of NOR removal with Fe2O3/g-C3N4 composites was about 0.6631 h(-1), and NOR photo-deegradation was still 86.7% after four cycles. The enhanced photocatalytic activity may be mainly attributed to the formation of S-scheme Fe2O3/g-C3N4 heterojunctions with built-in electric fields, which were beneficial to the separation and transfer of photostimulated charge carriers. Furthermore, a possible photo-degradation mechanism of NOR for S-scheme Fe2O3/g-C3N4 heterojunctions is described.
引用
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页数:13
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