[2+2]-Photocycloadditions of 1,4-Naphthoquinone Under Batch and Continuous-Flow Conditions

被引：1

作者：

Yaseen, Madyan A. ^{[1
,2
]}

Guo, Zhifang ^{[1
]}

Junk, Peter C. ^{[1
]}

Oelgemoeller, Michael ^{[1
,3
]}

机构：

[1] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4811, Australia

[2] Univ Samarra, Coll Educ, Samarra, Salah Al Deen, Iraq

[3] Univ Appl Sci, Hsch Fresenius gGmbH, Fac Chem & Biol, D-65510 Idstein, Germany

来源：

MOLECULES | 2024年 / 29卷 / 24期

关键词：

photocycloaddition; naphthoquinones; cyclobutanes; continuous-flow photochemistry; LIGHT; PHOTOCYCLOADDITION; PHOTOADDITION; CYCLOADDITION; CHEMISTRY; MECHANISM; QUINONES;

D O I：

10.3390/molecules29245920

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A series of [2+2]-photocycloadditions of 1,4-naphthoquinone with various alkenes and diphenylacetylene were investigated under batch and continuous-flow conditions. Acetone-sensitization furnished the corresponding photoadducts in good to excellent yields and purities. Compared to batch operations that demanded exhaustive irradiation times of 10-13 h, the flow process generally gave superior conversions and subsequently yields with a residence time of just 60 min. The structures of several photoaddition products were further determined by crystal structure analysis.

引用

页数：12

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