Silver-catalyzed regioselective synthesis of (E)-vinyl sulfones from nitroolefins and thiophenols

被引：0
作者：
Zhou, Kaiyang [1 ]
Wang, Xinyi [1 ]
Wang, Can [1 ]
Chen, Yunfeng [1 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Key Lab Green Chem Proc, Minist Educ, Wuhan 430205, Peoples R China
来源：
TETRAHEDRON LETTERS | 2025年 / 155卷
基金：
中国国家自然科学基金;
关键词：
( E ) -Vinyl sulfones; Silver-catalyzed; Thiophenols; DECARBOXYLATIVE SULFONYLATION; CINNAMIC-ACIDS; VINYL SULFONES; ALKENES; THIOLS; SULFONYLHYDRAZIDES; ARYL; AMINES; WATER;
D O I：
10.1016/j.tetlet.2024.155425
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient silver-catalyzed synthesis of (E)-vinyl sulfones was developed by denitrative radical cross-coupling of readily available thiophenols and nitroolefins. This reaction is initiated by generation of a thiyl radical or a sulfonyl radical from the thiophenol.
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页数：4
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