Research Progress on Preparation Methods of Single-atom Catalysts

Nowadays, we are facing increasingly serious energy and environmental problems, which urgently need more efficient chemical industry technologies to meet the requirements of low cost, high yield and sustainability. Developing efficient catalysts is of great significance for improving production efficiency, expanding economic benefits, optimizing energy structure, and ameliorating industrial structure. Single-atom catalysts (SACs), featuring unique properties arising from their single-atom dispersion on support surface, have demonstrated exceptional activity, selectivity and stability in energy catalysis, environmental catalysis and organic catalysis. Therefore, preparation methods and catalytic mechanisms of SACs have become a hot research topic on the international catalytic community. This review describes three strategies for preparing SACs: bottom-up synthesis, top-down synthesis and quantum dots cross-linking/self-assembly. Specifically, methods such as co-precipitation, immersion, atomic layer deposition, high-temperature atom thermal transfer, and high-temperature pyrolysis are presented in detail. These approaches precisely control the location and distribution of metal atoms, maximizing their utilization and catalytic efficiency. In addition, the challenges and development prospects faced by SACs related to stability, integrated control and industrial scalability are also summarized.