Improved oxidation behavior of M-20Cr-20Ta (M: Ni, Fe, Co) ternary alloys by formation of complex Cr-Ta-based oxides

被引：0
|
作者：
Tang, Chongchong [1 ]
Schaefer, Bjoern [1 ]
Schroer, Carsten [1 ]
Gorr, Bronislava [1 ]
机构：
[1] Karlsruhe Inst Technol KIT, Inst Appl Mat IAM AWP, D-76021 Karlsruhe, Germany
来源：
CORROSION SCIENCE | 2025年 / 249卷
关键词：
Ternary alloys; High-temperature oxidation; CrTaO 4 and CrTa 2 O 6; Oxidation kinetics; Microstructural evolution; HIGH-TEMPERATURE OXIDATION; HIGH-ENTROPY ALLOY; CYCLIC-OXIDATION; DIFFUSION; KINETICS; MICROSTRUCTURE; VOLATILIZATION; ADDITIONS; CHROMIUM; CRTAO4;
D O I：
10.1016/j.corsci.2025.112847
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The oxidation behavior and microstructural evolution of M-20Cr-20Ta (M: Ni, Fe, Co) alloys are investigated at 1000 degrees C and 1200 degrees C in Ar-20 vol% O2. High-temperature oxidation results in growth of bi-layered oxide scales, featuring an outer Cr2O3 layer and an inner Cr-Ta oxide layer. The Cr-Ta oxide layer consists of two distinct phases: CrTaO4 and CrTa2O6. Significant improvements in oxidation resistance are found for Co and Fe alloys, in consequence of formation of the Cr-Ta oxides. At 1200 degrees C, oxidation kinetics approach a cubic growth law after an initial transient stage, underscoring the exceptional protective capabilities of the Cr-Ta oxides.
引用
收藏
页数：12
相关论文
共 50 条
  • [21] Effect of Fe on corrosion of Ni-20Cr and Ni-30Cr alloys in wet CO2 gas at 650 and 700 °C
    Xie, Yun
    Zhang, Jianqiang
    Young, David J.
    Zheng, Weisen
    CORROSION SCIENCE, 2019, 154 : 129 - 143
  • [22] Microstructure and Phase Transformation in Fe20Co20Ni20Cr20B201xSix Alloys Prepared by Mechanical Alloying
    Zhang, Yicheng
    Ishimaru, Manabu
    Tokunaga, Tatsuya
    Era, Hidenori
    MATERIALS TRANSACTIONS, 2023, 64 (11) : 2568 - 2574
  • [23] Azo dye degradation behavior of AlFeMnTiM (M = Cr, Co, Ni) high-entropy alloys
    Wu, Shi-kai
    Pan, Ye
    Wang, Ning
    Lu, Tao
    Dai, Wei-ji
    INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2019, 26 (01) : 124 - 132
  • [24] Self-lubricating behavior of Fe22Co26Cr20Ni22Ta10 high-entropy alloy matrix composites
    Xiao, Wei-cheng
    Li, Kun
    Han, Liu-liu
    Liu, Yong
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2021, 31 (03) : 744 - 752
  • [25] Oxidation Behavior of γ′-Ni3Al-Based Ni-20Al-5Cr Alloys With and Without Reactive Elements Under Different Heating Conditions
    Chen, Wei-Ting
    Gleeson, Brian
    Heuer, Arthur
    OXIDATION OF METALS, 2019, 92 (3-4): : 137 - 150
  • [26] Oxidation behavior of a new wrought Ni-30Fe-20Cr based alloy at 750 °C in pure steam and the effects of alloyed yttrium
    Yang, Zhen
    Lu, Jin-tao
    Yang, Zheng
    Li, Yan
    Yuan, Yong
    Gu, Yue-feng
    CORROSION SCIENCE, 2017, 125 : 106 - 113
  • [27] Tribological behavior of boronized Fe40Mn20Cr20Ni20 high-entropy alloys in high temperature
    Yang, Rui
    Guo, Xin
    Yang, Huijun
    Qiao, Junwei
    SURFACE & COATINGS TECHNOLOGY, 2023, 464
  • [28] Dynamic impact behavior and deformation mechanisms of Cr26Mn20Fe20Co20Ni14 high-entropy alloy
    Jiang, Wei
    Gao, Xuzhou
    Guo, Yazhou
    Chen, Xiang
    Zhao, Yonghao
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2021, 824
  • [29] Microstructure and mechanical properties of Co19Cr20Fe20Mn21Ni19 and Co19Cr20Fe20Mn21Ni19Nb0.06C0.8 high-entropy/compositionally-complex alloys after annealing
    Abbasi, Erfan
    Dehghani, Kamran
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2020, 772
  • [30] Scaling behavior of four ternary Co-20Ni-based alloys containing 3/5 wt% Al or 8/15 wt% Cr in 1 Atm O2 at 800-900 °C
    Lv, Y. L.
    Ren, Y. J.
    Wang, W.
    Zhou, L. B.
    Chen, J.
    Huang, J.
    Tao, M. S.
    Niu, Y.
    CORROSION SCIENCE, 2022, 199
12345