Synthesis of low-cost microporous activated carbon adsorbents for CO2 capture from Palmyra palm fruit shell waste biomass

被引:4
|
作者
Swapna, Shobanaboyina [1 ]
Ramudu, Manne Parusha [2 ]
Reddy, Police Vishnu Vardhan [3 ]
Kumar, Gande Ravi [4 ]
Bindu, Gaddameedi Hima [3 ]
Prathap, Challa [5 ]
Mallesh, Dosali [3 ]
机构
[1] Osmania Univ, Nizam Coll, Dept Chem, Hyderabad, India
[2] Univ Coll Sci, Dept Chem, Hyderabad, India
[3] CVR Coll Engn, Dept H&S Chem, Hyderabad, India
[4] Vardhaman Coll Engn, Dept Chem, Hyderabad, India
[5] Mallareddy Engn Coll Women, Dept Chem, Hyderabad, India
关键词
activated carbon; adsorption; carbon dioxide; carbonization; Palmyra palm fruit shell; PRESSURE SWING ADSORPTION; HIGH-SURFACE-AREA; POROUS CARBON; KOH; KINETICS;
D O I
10.1002/jccs.202400261
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using chemical activation techniques at dissimilar carbonization temperatures, activated carbon adsorbents were produced from Palmyra palm fruit biomass in this work. X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, laser Raman spectroscopy, scanning electron microscopy, CHNS-elemental analysis, and N2 adsorption studies were among the characterization techniques used to assess the characteristics of the carbon adsorbents. The carbon adsorbents from Palmyra palm fruit were used to absorb CO2 in a temperature range of 25-70 degrees C. The findings of the characterization showed that these carbons have a large surface area and microporosity. The temperature of carbonization and the activating agent had an impact on the surface characteristics. The samples with the highest adsorption capacity, 4.70 mmol/g at 25 degrees C, were the activated carbons made by treating them with KOH and then carbonizing them at 750 degrees C. The physicochemical properties of the adsorbents provided an explanation for their high adsorption capacity. The adsorbents showed simple desorption and maintained constant activity during ten cycles of recycling.
引用
收藏
页码:1435 / 1447
页数:13
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