Transformation of metal-organic frameworks (MOFs) under different factors

被引：6

作者：

Xiang, Yilei ^{[2
]}

Wei, Suosu ^{[3
]}

Wang, Taoxiang ^{[1
]}

Li, Huang ^{[1
]}

Luo, Yan ^{[1
]}

Shao, Bing ^{[6
]}

Wu, Ningyuan ^{[5
]}

Su, Yiji ^{[4
]}

Jiang, Linbin ^{[2
]}

Huang, Jin ^{[1
]}

机构：

[1] Guangxi Med Univ, Pharmaceut Coll, Nanning 530021, Peoples R China

[2] Guangxi Univ, Guangxi Coll & Univ Key Lab Appl Chem Technol & Re, Sch Chem & Chem Engn, Guangxi Key Lab Petrochem Resource Proc & Proc Int, Nanning 530004, Peoples R China

[3] Guangxi Acad Med Sci, Peoples Hosp Guangxi Zhuang Autonomous Reg, Dept Sci Cooperat, Nanning 530021, Peoples R China

[4] Guangxi Med Univ, Affiliated Hosp 1, Nanning 530021, Peoples R China

[5] Guangxi Med Univ, Life Sci Inst, Nanning 530021, Peoples R China

[6] Guangxi Normal Univ, Sch Chem & Pharm, Guilin 541004, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2025年 / 523卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic frameworks; Morphological transformation; Structural transformation; Stimulating factors; Structure-property relationship; STRUCTURAL TRANSFORMATION; THERMAL-DECOMPOSITION; HYDROGEN STORAGE; DESIGN; ADSORPTION; CO2; SITES; ACID; STABILITIES; TEMPERATURE;

D O I：

10.1016/j.ccr.2024.216263

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-organic frameworks (MOFs) have been widely used in physics, chemistry, and medicine due to their large porosity and adjustable pores, high specific surface area, and good chemical and thermal stability. Most MOFs are structurally stable, but they still undergo morphological transformation and structural transformation under the stimulating factors, and these transformations are unavoidable. In this paper, we focus on the transformations of MOF under the different factors, such as chemistry, electrochemistry, photochemistry, thermochemistry and so on. Structure-property relationship is also discussed. What's more, the future development trends and challenges of MOF are also described.

引用

页数：32

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