Investigation of the Influence of Alloying Elements Ni, Cr, Co and Mo on the Crystallization Process, Phase Composition and Corrosion Resistance of AlSi25Cu4Cr and AlSi25Cu5Cr Alloys

被引:0
作者
Dochev, Boyan [1 ]
Dimova, Desislava [1 ]
Trojan, Karel [2 ]
Capek, Jiri [2 ]
Kamarska, Kalina [1 ]
Chuchulska, Bozhana [3 ]
机构
[1] Tech Univ Sofia, Fac Mech Engn, Dept Mech Engn & Technol, Branch Plovdiv, Plovdiv 4000, Bulgaria
[2] Czech Tech Univ, Fac Nucl Sci & Phys Engn, Trojanova 13, Prague 12000, Czech Republic
[3] Med Univ Plovdiv, Fac Dent Med, Dept Prosthet Dent Med, Plovdiv 4000, Bulgaria
关键词
hypereutectic aluminum-silicon alloys; thermal analysis; phase composition; corrosion resistance; AL-SI ALLOYS; MECHANICAL-PROPERTIES; GRAIN-REFINEMENT; MICROSTRUCTURE; ALUMINUM; SILICON; IRON; SR; ADDITIONS;
D O I
10.3390/ma18040907
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To increase the mechanical and improve the operational properties of the AlSi25Cu4Cr and AlSi25Cu5Cr alloys, combinations of the alloying elements Ni, Co and Mo were used. The AlSi25Cu4Cr alloy was additionally alloyed with both Ni and Mo and Ni, Co and Mo, and the AlSi25Cu5Cr alloy was alloyed with Co and Mo in different concentrations. The dental alloys "wiron light" and "wironit" were used to introduce the elements Ni, Co, Mo, as well as additional amounts of Cr into the composition of the base compositions. The thermal analysis recorded a decrease in the liquidus and solidus temperatures of the base alloys, as well as a narrowing of their crystallization temperature range as a result of the added alloying elements. The influence of the used chemical elements on the phase composition of the alloys was established by X-ray diffraction. The elements Cr and Mo do not form secondary strengthening phases but dissolve in the alpha-solid solution. The results of the corrosion tests conducted in 1 M HCl solution and 1 M H2SO4 solution for 336 h and 504 h show that the elements Ni, Co and Mo improve the corrosion resistance of the alloys.
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页数:16
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共 53 条
[1]  
Kandeva M., Dochev B., Dimova D., Zagorski M., Kasabov P., Investigation of the wear resistance of tribological systems composed of aluminium-silicon alloys: PART 1, J. Balk. Tribol. Assoc, 30, pp. 59-66, (2024)
[2]  
Kandeva M., Dochev B., Dimova D., Zagorski M., Kasabov P., Investigation of the wear resistance of tribological systems composed of aluminium-silicon alloys: PART 2, J. Balk. Tribol. Assoc, 30, pp. 208-217, (2024)
[3]  
Piston materials, Pistons and Engine Testing. ATZ/MTZ-Fachbuch, (2012)
[4]  
Miladinovic S., Stojanovic B., Gajevic S., Vencl A., Hypereutectic Aluminum Alloys and Composites: A Review
[5]  
Joseph O.O., Olubambi P.A., Joseph O.O., Edun B.M., Okeniyi J.O., Abioye O.P., Effects of Alloying on Aluminium-Silicon Alloys—A Review, IOP Conf. Ser. Mater. Sci. Eng, 1107, (2021)
[6]  
Efzan M.N.E., Kong H.J., Kok C.K., Review: Effect of Alloying Element on Al-Si Alloys, Adv. Mater. Res, 845, pp. 355-359, (2013)
[7]  
Abalymov V.R., Zhereb V.P., Kleimenov Y.A., Antonov M.M., Effect of Heat Treatment on the Structure and Mechanical Properties of Eutectic Silumin Alloyed with Magnesium, Met. Sci. Heat Treat, 63, pp. 291-296, (2021)
[8]  
Elsharkawi E.A., Ibrahim M.F., Samuel A.M., Doty H.W., Samuel F.H., Understanding the Effect of Be Addition on the Microstructure and Tensile Properties of Al–Si–Mg Cast Alloys, Int. J. Met, 16, pp. 1777-1795, (2022)
[9]  
Liu X., Wang C., Zhang S., Song J., Zhou X., Zha M., Wang H., Fe-Bearing Phase Formation, Microstructure Evolution, and Mechanical Properties of Al-Mg-Si-Fe Alloy Fabricated by the Twin-Roll Casting Process, J. Alloys Compd, 886, (2021)
[10]  
Furui M., Kitamura T., Ishikawa T., Ikeno S., Saikawa S., Sakai N., Evaluation of Age Hardening Behavior Using Composite Rule and Microstructure Observation in Al-Si-Mg Alloy Castings, Mater. Trans, 52, pp. 1163-1167, (2011)