Fabrication of high-performance asymmetric supercapacitor device based on CuS with marigold flower like framework

被引:2
作者
Samdhyan, Kajal [1 ]
Chand, Prakash [2 ]
Anand, Hardeep [1 ]
机构
[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, India
[2] Natl Inst Technol, Dept Phys, Kurkshetra 136119, India
关键词
Copper sulfide; Solvent; Specific capacitance; Asymmetric supercapacitor device; HIERARCHICAL STRUCTURES; CONTROLLABLE SYNTHESIS; NANOPARTICLES; ELECTRODE;
D O I
10.1016/j.est.2024.114719
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A solvent regulated approach was utilized for creating copper sulfide of distinct morphologies and employed as an electrode in three and two electrode configurations. X-ray diffraction, FESEM and TEM revealed the crystalline structure and marigold flower like morphology of copper sulfide in ethylene glycol. The marigold flower like CuS outperforms in terms of electrochemical performance, with an excellent capacitance of 631.2 F/g at 1 A/ g of current density. Furthermore, a supercapacitor device has been constructed with a potential window of 1.4 V, exhibited 301.23 F/g of capacitance at 10 A/g. This device displays a desired 82 Wh/kg of energy density when the power density is 2.9 kW/kg. The device maintained cyclic stability of 82 % during 2500 GCD cycles at 20 A/g. Two devices connected in series light up different colours of LEDs. These favourable electrochemical results strongly suggest that the marigold flower-like CuS electrode has excellent potential for use in energy storage applications.
引用
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页数:13
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共 61 条
[1]   Fabrication of Phyllanthus emblica leaves derived high-performance activated carbon-based symmetric supercapacitor with excellent cyclic stability [J].
Agrawal, Anant ;
Gaur, Anurag ;
Kumar, Ashavani .
JOURNAL OF ENERGY STORAGE, 2023, 66
[2]   Fabrication of robust Fe2O3@NiCo2O4 core-shell composite with spikey surface for high-performance asymmetric solid-state supercapacitor [J].
Agrawal, Anant ;
Kumar, Ashavani ;
Gaur, Anurag .
JOURNAL OF ENERGY STORAGE, 2022, 56
[3]   Synthesis and characterization of ultralong copper sulfide nanowires and their electrical properties [J].
Anichini, Cosimo ;
Czepa, Wlodzimierz ;
Aliprandi, Alessandro ;
Consolaro, Valentina Girelli ;
Ersen, Ovidiu ;
Ciesielski, Artur ;
Samori, Paolo .
JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (36) :12133-12140
[4]   Facile synthesis of plate-like copper sulfide powder as an electrode material for high-performance supercapacitors [J].
Barqi, J. ;
Masoudpanah, S. M. ;
Bafghi, M. Sh. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2020, 31 (20) :17614-17623
[5]   Electrochemical hydrogen-storage performance of copper sulfide micro-hexagons [J].
Bhat, Karthik S. ;
Nagaraja, H. S. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (07) :5530-5536
[6]   A facile one step hydrothermal induced hexagonal shaped CuS/rGO nanocomposites for asymmetric supercapacitors [J].
BoopathiRaja, R. ;
Parthibavarman, M. ;
Prabhu, S. ;
Ramesh, R. .
MATERIALS TODAY-PROCEEDINGS, 2020, 26 :3507-3513
[7]   Electrochemical Impedance Spectroscopy in the Characterisation and Application of Modified Electrodes for Electrochemical Sensors and Biosensors [J].
Brett, Christopher M. A. .
MOLECULES, 2022, 27 (05)
[8]   Chemically synthesized copper sulfide nanoflakes on reduced graphene oxide for asymmetric supercapacitors [J].
Bulakhe, Ravindra N. ;
Alfantazi, Akram ;
Lee, Yong Rok ;
Lee, Moonyong ;
Shim, Jae-Jin .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2021, 101 :423-429
[9]   Solvent-regulated synthesis and phosphating of nickel-cobalt bimetal organic framework microflowers with hierarchical structure for high-performance supercapacitors [J].
Cao, Yujuan ;
Wu, Ning ;
Li, Cuiliu ;
Chen, Yuan ;
Zhang, Hao ;
Guo, Hao ;
Yang, Wu .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2023, 658
[10]  
Chand P., 2021, Chem. Phys. Lett, V777, P138742