Process electrification by magnetic heating of catalyst
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作者:
Pavelic, Jakov-Stjepan
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机构:
Natl Inst Chem, Dept Catalysis & Chem React Engn, Hajdrihova 19, Ljubljana 1000, Slovenia
Univ Ljubljana, Fac Chem & Chem Technol, Vecna Pot 113, Ljubljana 1000, SloveniaNatl Inst Chem, Dept Catalysis & Chem React Engn, Hajdrihova 19, Ljubljana 1000, Slovenia
Pavelic, Jakov-Stjepan
[1
,2
]
Gyergyek, Saso
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机构:
Jozef Stefan Inst, Dept Mat Synth, Jamova Cesta 39, Ljubljana 1000, SloveniaNatl Inst Chem, Dept Catalysis & Chem React Engn, Hajdrihova 19, Ljubljana 1000, Slovenia
Gyergyek, Saso
[3
]
Likozar, Blaz
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机构:
Natl Inst Chem, Dept Catalysis & Chem React Engn, Hajdrihova 19, Ljubljana 1000, Slovenia
Univ Ljubljana, Fac Chem & Chem Technol, Vecna Pot 113, Ljubljana 1000, SloveniaNatl Inst Chem, Dept Catalysis & Chem React Engn, Hajdrihova 19, Ljubljana 1000, Slovenia
Process Electrification;
Magnetic heating;
Catalysis;
Heat transfer;
IRON CARBIDE NANOPARTICLES;
CO2;
HYDROGENATION;
NI-SPINEL;
HYPERTHERMIA;
COMPOSITE;
FLOW;
ENHANCEMENT;
TECHNOLOGY;
GROWTH;
D O I:
10.1016/j.cej.2024.158928
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Electrification of the chemical and energy sector is a crucial step in the transition towards a carbon neutral society. Electrocatalysis is one way to selectively steer a reaction towards the desired products which relies on the electric field effects instead of temperature, but there is another way to solely heat the reaction site. Magnetic or induction heating of magnetic nanoparticles embedded within the catalyst can selectively heat the catalyst at the reaction site. Furthermore, such rapid and selective heating enables a construction of decentralised, intermediate-scale, adaptable, containerised and responsive units, capable of flexible operation as per the Europen Union's new industrial paradigm. The possibly to utilize intermittent renewable energy and to operate reactors in highly dynamically responsive manner leads to energy efficiency, safer operation, reduced energy costs in downstream processing, keeping bulk fluid cold(er) compared to the catalyst grain to mention a few advantages. Recently, this concept has been successfully applied and reported but only in a relatively limited number of studies, which are reported and thoroughly reviewed in this work. This review aims to highlight and critically evaluate recent developments of magnetic materials used in magnetically heated catalysis and represent their magnetic and chemical properties in combination with an overview of reported chemical conversions. It can serve as guide to select optimal magnetic material for a targeted chemical conversion, highlighting (also schematically) their potential and restriction of use.