Nanostructured single-atom catalysts derived from natural building blocks

被引:5
作者
Zhang, Yajing [1 ,2 ]
Yang, Guobin [1 ,3 ]
Wang, Jin [1 ,4 ]
Zhao, Bin [5 ]
He, Yunxiang [1 ,2 ]
Guo, Junling [1 ,2 ,6 ]
机构
[1] Sichuan Univ, Coll Biomass Sci & Engn, BMI Ctr Biomass Mat & Nanointerfaces, Chengdu 610065, Sichuan, Peoples R China
[2] Sichuan Univ, Natl Engn Lab Clean Technol Leather Manufacture, Chengdu 610065, Sichuan, Peoples R China
[3] Harbin Inst Technol, Weihai Marine Organism & Med Technol Res Inst, Coll Marine Sci & Technol, Weihai 264209, Shandong, Peoples R China
[4] Univ Chicago, Pritzker Sch Mol Engn, Chicago, IL 60637 USA
[5] Aalto Univ, Sch Chem Engn, Dept Bioprod & Biosyst, FI-02150 Espoo, Finland
[6] Univ British Columbia, Bioprod Inst, Dept Chem & Biol Engn, Vancouver, BC V6T 1Z4, Canada
来源
EES CATALYSIS | 2024年 / 2卷 / 02期
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
DOPED POROUS CARBON; OXYGEN REDUCTION REACTION; SPENT COFFEE GROUNDS; SALT MELT SYNTHESIS; MOLTEN CARBONATES; GENERAL-APPROACH; SITE CATALYSTS; EFFICIENT; FE; BIOMASS;
D O I
10.1039/d3ey00265a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Single-atom catalysts (SACs) exhibit maximized atomic utilization with individual metal atoms anchored on supporting materials, where the pursuit of high performance and low cost presents challenges. In this case, carbon provides structural versatility and customizable properties as a supporting material, which has been extensively studied. Biomass materials have emerged as promising precursors for the preparation of carbon-based SACs due to their renewable nature for sustainability, abundance for low cost, and high carbon content for advanced performance. In this review, representative synthesis strategies and advanced characterization techniques for biomass-derived CS-SACs are summarized, which facilitate the establishment of guidelines for the rational design and fabrication of biomass-derived SACs. In addition, we provide a timely and comprehensive discussion on the use of a broad range of natural biomass for SACs, with insights into the specific carbon nature of biomass resources, including their carbon structures, metal-carbon coordination environment, and center metal species. Furthermore, the application areas of biomass-derived CS-SACs in various catalytic processes are reviewed. Overall, the challenges and future perspectives of using biomass as precursors for SACs are outlined. We hope that this review can offer a valuable overview of the current knowledge, recent progress, and directions of biomass-derived SACs.
引用
收藏
页码:475 / 506
页数:32
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