Crystal structure and Hirshfeld surface analysis of (nitrato-κ2O,O')(1,4,7,10-tetraazacyclododecane-κ4N)nickel(II) nitrate

被引：0

作者：

Reibenspies, Joseph ^{[1
]}

Small, Nadia ^{[1
]}

Bhuvanesh, Nattamai ^{[1
]}

Chiarella, Gina ^{[2
]}

Salazar, Vivian ^{[2
]}

Pery, Breayshia ^{[2
]}

Smith, Rukiyah ^{[2
]}

Toole, Deja ^{[2
]}

Hewage, Shamika ^{[2
]}

Fernando, Harschica ^{[2
]}

Reinheimer, Eric ^{[3
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Prairie View A&M Univ, Prairie View, TX 77446 USA

[3] Rigaku Americas Corp, The Woodlands, TX 77381 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2024年 / 80卷

关键词：

crystal structure; cyclen; nickel; nitrate; CYCLEN; COORDINATION; COMPLEXES;

D O I：

10.1107/S2056989024009496

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Ni(C8H20N4)(NO3)]NO3, at room temperature, has monoclinic (P2(1)/n) symmetry. The structure displays intermolecular hydrogen bonding. The nickel displays a distorted bipyramidal geometry with the symmetric bidentate bonded nitrate occupying an equatorial site. The 1,4,7,10-tetraazacyclododecane (cyclen) backbone has the [4,8] configuration, with three nitrogen-bound H atoms directed above the plane of the nitrogen atoms towards the offset nickel atom with the fourth nitrogen-bound hydrogen directed below from the plane of the nitrogen atoms. The nitrate anion O atoms are seen to hydrogen bond to the H atoms bound to the N atoms of the ligand.

引用

页码：1157 / +

页数：9

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