Lignin charcoal/preparation of chitosan composite membrane and H2S adsorption properties

被引:0
作者
Yang, Dongdong [1 ]
Yang, Ying [1 ]
Li, Fen [1 ]
Zheng, Menglong [1 ]
Chen, Huiyu [1 ]
Wang, Ruiying [1 ]
Li, Qiushuang [1 ]
机构
[1] Harbin Univ Sci & Technol, Key Lab Green Chem Engn & Technol, Coll Heilongjiang Prov, Sch Mat Sci & Chem Engn, Harbin 150080, Peoples R China
基金
中国国家自然科学基金;
关键词
hydrogen sulfide; lignin charcoal; chitosan; membrane adsorption; POLYETHYLENE-GLYCOL; BIOGAS;
D O I
10.1515/polyeng-2024-0151
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, chitosan was first used as the raw material for filmmaking, and the film-forming conditions were optimized to prepare six kinds of chitosan-based membranes, and then charcoal composite membrane materials were prepared by adding different amounts of lignin charcoal to fill in the base membranes; the adsorption performance of the composite membrane was analyzed using H2S as the target, and the mechanical properties and structure of the composite membrane were explored using various testing techniques. The experimental results showed that the chitosan-based membrane could adsorb a certain amount of H2S due to its hydroxyl-rich surface. When lignin carbon was added to it, and with the increase of the content of lignin carbon, the performance of the membrane adsorption of H2S was improved, but the mechanical properties decreased, and in a comprehensive comparison of the adsorption performance and mechanical properties of the composite membrane, which had a better adsorption length of H2S adsorption of 84 min and the tensile strength of 1.65 MPa. The pore structure in the composite membrane due to microphase separation and the exposure of oxygen-containing functional groups on the surface of the base membrane and charcoal were the main reasons for the effective retention of H2S.
引用
收藏
页码:165 / 175
页数:11
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共 21 条
  • [1] 13X Ex-Cu zeolite performance characterization towards H2S removal for biogas use in molten carbonate fuel cells
    Barelli, Linda
    Bidini, Gianni
    Micoli, Luca
    Sisani, Elena
    Turco, Maria
    [J]. ENERGY, 2018, 160 : 44 - 53
  • [2] Structure and Properties of Melt-Stretching Polypropylene/Silicon Dioxide Compound Microporous Membrane
    Cai, Qi
    Xu, Ruijie
    Chen, Xiande
    Chen, Changbin
    Mo, Haibin
    Lei, Caihong
    [J]. POLYMER COMPOSITES, 2016, 37 (09) : 2684 - 2691
  • [3] A state-of-the-art review on capture and separation of hazardous hydrogen sulfide (H2S): Recent advances, challenges and outlook*
    Chan, Yi Herng
    Lock, Serene Sow Mun
    Wong, Mee Kee
    Yiin, Chung Loong
    Loy, Adrian Chun Minh
    Cheah, Kin Wai
    Chai, Slyvester Yew Wang
    Li, Claudia
    How, Bing Shen
    Chin, Bridgid Lai Fui
    Chan, Zhe Phak
    Lam, Su Shiung
    [J]. ENVIRONMENTAL POLLUTION, 2022, 314
  • [4] Effects of polyethylene glycol on membrane formation and properties, of hydrophilic sulfonated polyphenylenesulfone (sPPSU) membranes
    Feng, Yingnan
    Han, Gang
    Chung, Tai-Shung
    Weber, Martin
    Widjojo, Natalia
    Maletzko, Christian
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2017, 531 : 27 - 35
  • [5] Methods for preparation and activation of activated carbon: a review
    Heidarinejad, Zoha
    Dehghani, Mohammad Hadi
    Heidari, Mohsen
    Javedan, Gholamali
    Ali, Imran
    Sillanpaa, Mika
    [J]. ENVIRONMENTAL CHEMISTRY LETTERS, 2020, 18 (02) : 393 - 415
  • [6] Recyclable nanocomposites for carbon dioxide fixation and membrane separation using waste polycarbonate
    Huang, Ying-Chi
    Chen, Li-Fan
    Huang, Yu-Hsiang
    Hu, Chien-Chieh
    Wu, Chien-Hsin
    Jeng, Ru-Jong
    [J]. CHEMICAL ENGINEERING JOURNAL, 2023, 452
  • [7] Production and Physiological Effects of Hydrogen Sulfide
    Kimura, Hideo
    [J]. ANTIOXIDANTS & REDOX SIGNALING, 2014, 20 (05) : 783 - 793
  • [8] Study on the adsorption performance and regeneration of lignin- derived graphitic carbon for H2S
    Li, Fen
    Wang, Ruiying
    Yang, Ying
    Zheng, Menglong
    Li, Qiushuang
    Yang, Dongdong
    Chen, Huiyu
    [J]. PARTICUOLOGY, 2024, 94 : 197 - 210
  • [9] Oxidation mechanisms of H2S by oxygen and oxygen-containing functional groups on activated carbon
    Li, Yuran
    Lin, Yuting
    Xu, Zhicheng
    Wang, Bin
    Zhu, Tingyu
    [J]. FUEL PROCESSING TECHNOLOGY, 2019, 189 : 110 - 119
  • [10] Hydrogen sulfide removal from natural gas using membrane technology: a review
    Ma, Yulei
    Guo, Hongfang
    Selyanchyn, Roman
    Wang, Bangda
    Deng, Liyuan
    Dai, Zhongde
    Jiang, Xia
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (36) : 20211 - 20240