Transition metal-catalyzed P(O)-H alkenylation, allenylation and alkynylation reactions: A recent trend

被引：0

作者：

Yang, Haoran ^{[1
]}

Liu, Shaoqing ^{[1
]}

Shen, Ruwei ^{[1
]}

Han, Li-Biao ^{[2
,3
]}

机构：

[1] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China

[2] Shaoxing Univ, Coll Chem & Chem Engn, Res Ctr Adv Catalyt Mat & Funct Mol Synth, Shaoxing 312000, Peoples R China

[3] Zhejiang Yangfan New Mat Co Ltd, Shangyu 312369, Peoples R China

来源：

TETRAHEDRON | 2025年 / 170卷

基金：

中国国家自然科学基金;

关键词：

Organophosphorus; Transition metal catalysis; Alkynes; Phosphorylation; Hydrogen phosphoryl compounds; FACILE OXIDATIVE ADDITION; SECONDARY PHOSPHINE OXIDES; SPHINGOSINE KINASE 1; C-H/P-H; TERMINAL ALKYNES; EFFICIENT ROUTE; PROPARGYLIC SUBSTITUTION; STEREOSELECTIVE HYDROPHOSPHINYLATION; DIARYLPHOSPHINE OXIDES; SELECTIVE INHIBITORS;

D O I：

10.1016/j.tet.2024.134388

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphorus-containing unsaturated hydrocarbons, including alkenyl, allenyl, and alkynyl phosphoryl compounds, constitute a significant subclass of organophosphorus intermediates that have extensive applications in organic synthesis and related fields. Among various synthetic approaches, the transition metal-mediated reactions of the readily accessible hydrogen phosphoryl chemicals with alkynes stand out as one of the most efficient and straightforward methods for their preparation. Here, we summarize the recent advancement in transition metal-catalyzed P(O)-H alkenylation, allenylation, and alkynylation reactions to reflect a current research trend of the field.

引用

页数：19

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