Selective production of high-value fuel via catalytic upgrading of bio-oil over nitrogen-doped carbon-alumina hybrid supported cobalt catalysts

被引:4
|
作者
Peng, Qin [1 ,2 ,3 ]
Jiang, Xia [1 ]
Cao, Guangmei [1 ]
Xie, Tianqiao [1 ,2 ]
Jin, Ziheng [1 ]
Xie, Lingling [2 ]
Gan, Fengli [2 ]
Ma, Shenggui [1 ]
Peng, Mingming [4 ]
机构
[1] Sichuan Univ, Coll Carbon Neutral Future Technol, Chengdu 610065, Peoples R China
[2] Sichuan Univ, Coll Architecture & Environm, Chengdu 610065, Peoples R China
[3] Chongqing Univ Arts & Sci, Chongqing Key Lab Environm Mat & Remediat Technol, Chongqing 402160, Peoples R China
[4] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, 2-24-16 Nakacho, Koganei, Tokyo 1848588, Japan
关键词
Biochar; N doping; Hydrodeoxygenation; Hydrocarbon fuel; DFT calculations; LIGNIN-DERIVED PHENOLS; TEMPERATURE HYDRODEOXYGENATION; RU NANOPARTICLES; BIOMASS; EFFICIENT; HYDROGENATION; PYROLYSIS; POWDER; WASTE; METAL;
D O I
10.1016/j.biortech.2024.131059
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Bio-oil derived from biomass fast pyrolysis can be upgraded to gasoline and diesel alternatives by catalytic hydrodeoxygenation (HDO). Here, the novel nitrogen-doped carbon-alumina hybrid supported cobalt (Co/NCAn, n , n = 1, 2.5, 5) catalyst is established by a coagulation bath technique. The optimized Co/NCA2.5 2.5 catalyst presented 100 % conversion of guaiacol, high selectivity to cyclohexane (93.6 %), and extremely high deoxygenation degree (97.3 %), respectively. Therein, the formation of cyclohexanol was facilitated by stronger binding energy and greater charge transfer between Co and NC which was unraveled by density functional theory calculations. In addition, the appropriate amount of Lewis acid sites enhanced the cleavage of the C-O bond in cyclohexanol, finally resulting in a remarkable selectivity for cyclohexane. Finally, the Co/NCA2.5 2.5 catalyst also exhibited excellent selectivity (93.1 %) for high heating value hydrocarbon fuel in crude bio-oil HDO. This work provides a theoretical basis on N dopants collaborating alumina hybrid catalysts for efficient HDO reaction.
引用
收藏
页数:10
相关论文
共 10 条
  • [1] Chemoselective Hydrodeoxygenation of Carboxylic Acids to Hydrocarbons over Nitrogen-Doped Carbon-Alumina Hybrid Supported Iron Catalysts
    Li, Jiang
    Zhang, Junjie
    Wang, Shuai
    Xu, Guangyue
    Wang, Hao
    Vlachos, Dionisios G.
    ACS CATALYSIS, 2019, 9 (02) : 1564 - 1577
  • [2] Biomass to hydrogen via catalytic steam reforming of bio-oil over Ni-supported alumina catalysts
    Seyedeyn-Azad, F.
    Salehi, E.
    Abedi, J.
    Harding, T.
    FUEL PROCESSING TECHNOLOGY, 2011, 92 (03) : 563 - 569
  • [3] Gas-phase hydrodeoxygenation of bio-oil model compound over nitrogen-doped carbon-supported palladium catalyst
    Liu, Chunjiang
    Zhou, Chaoqun
    Wang, Yu
    Liu, Xinghua
    Zhu, Linyu
    Ma, Hao
    Zhou, Zhongyue
    Qi, Fei
    PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2021, 38 (03) : 4345 - 4353
  • [4] Selectively catalytic upgrading of bio-oil to aromatic hydrocarbons over Zn, Ce or Ni-doped mesoporous rod-like alumina catalysts
    Karnjanakom, Surachai
    Bayu, Asep
    Hao, Xiaogang
    Kongparakul, Suwadee
    Samart, Chanatip
    Abudula, Abuliti
    Guan, Guoqing
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 421 : 235 - 244
  • [5] A modeling strategy investigation for selective hydrodeoxygenation biomass upgrading of vanillin via metal supported on pyridinic and pyrrolic nitrogen-doped carbon catalysts
    Xiao, Yi
    Liu, Li
    Zhang, Wei-Bin
    Han, Li-Li
    RARE METALS, 2024, 43 (12) : 6460 - 6472
  • [6] A modeling strategy investigation for selective hydrodeoxygenation biomass upgrading of vanillin via metal supported on pyridinic and pyrrolic nitrogen-doped carbon catalysts
    Yi Xiao
    Li Liu
    WeiBin Zhang
    LiLi Han
    Rare Metals, 2024, 43 (12) : 6460 - 6472
  • [7] Sustainable Production of High-Value Chemicals from Selective Hydrogenolysis of Lignin Catalyzed by Co-Pd Bimetallic Supported on Nitrogen-Doped Carbon Spheres
    Liang, Qiqi
    Fu, Yan
    Qiu, Shuaishuai
    Chang, Jie
    ENERGY & FUELS, 2024, 38 (12) : 10993 - 11005
  • [8] Cobalt oxides nanoparticles supported on nitrogen-doped carbon nanotubes as high-efficiency cathode catalysts for microbial fuel cells
    Yang, Wei
    Lu, Jia En
    Zhang, Yudong
    Peng, Yi
    Mercado, Rene
    Li, Jun
    Zhu, Xun
    Chen, Shaowei
    INORGANIC CHEMISTRY COMMUNICATIONS, 2019, 105 : 69 - 75
  • [9] Enhanced bio-oil production from Co-pyrolysis of cotton seed and polystyrene waste; fuel upgrading by metal-doped activated carbon catalysts
    Mousavi, Mahshid Vaghar
    Rezvani, Behnam
    Hallajisani, Ahmad
    JOURNAL OF THE ENERGY INSTITUTE, 2025, 119
  • [10] In-situ bio-oil directional conversion mechanism of catalytic biomass pyrolysis over nitrogen-doped carbon preparation by grading of nitrogen-rich cow dung
    Yang, Youming
    Wang, Jiaofei
    Zhang, Yujie
    Lv, Peng
    Su, Weiguang
    Bai, Yonghui
    Song, Xudong
    Yu, Guangsuo
    Yang, Guang
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2024, 178