A coumarin based "turn-on" type fluorescent probe for the detection of Cu2+ with mechanochromic property

被引：1

作者：

Fu, Shuai ^{[1
]}

Deng, Linlong ^{[1
]}

Xue, Lei ^{[1
]}

Gao, Yunke ^{[1
]}

Cheng, Yihan ^{[1
]}

Wang, Haibin ^{[1
]}

机构：

[1] Ningxia Normal Univ, Coll Chem & Chem Engn, Ningxia Key Lab Green Catalyt Mat & Technol, Guyuan 756000, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2025年 / 1334卷

关键词：

Coumarin; Fluorescent probe; Cu2+; Mechanochromic property;

D O I：

10.1016/j.molstruc.2025.141938

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study presents the design and synthesis of a novel fluorescent probe, (Z)-N'-[[7-(diethylamino)-2-oxo-2H- chromen-4-yl]methylene]-2-hydroxybenzohydrazide (FS). FS demonstrated a pronounced "turn on" type cyan fluorescence upon the addition of Cu2+ in a DMSO/PBS solution (1 mM, pH = 7.4, V: V = 1:1). The detection of Cu2+ by FS displayed high selectivity, strong anti-interference capabilities, and a low detection limit of 2.46 x 10(-8) M. The binding ratio of FS to Cu2+ was determined to be 1:1 according to the Job's plot and DFT calculation while the binding constant was calculated to be 6.20 x 10(4) M-1. Additionally, the recognition mechanism of FS for Cu(2+)was further elucidated through ESI-MS and 1H NMR titration analyses. Moreover, FS exhibited mechanochromic property, transforming from yellow to orange fluorescence upon grinding, with the emission wavelength shifting from 551 nm to 597 nm. Meanwhile, the original state could be restored through fumigation with ethanol vapor, and this process was repeatable. Furthermore, FS demonstrated potential applications for Cu2+ detection and in the production of pressure-sensitive writing fluorescent display materials.

引用

页数：11