Synthesis of the aggregation pheromone of Tribolium castaneum

被引：0

作者：

An, Biyu ^{[1
]}

Wang, Xueyang ^{[1
]}

Jiao, Ao ^{[2
]}

Bian, Qinghua ^{[1
]}

Zhong, Jiangchun ^{[1
]}

机构：

[1] China Agr Univ, Dept Appl Chem, 2 West Yuanmingyuan Rd, Beijing 100193, Peoples R China

[2] Shijiazhuang Camford Royal Sch, Shijiazhuang 050800, Heibei, Peoples R China

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 21卷

关键词：

aggregation pheromone; chiral; 2-methyloxirane; red flour beetle; total synthesis; RED FLOUR BEETLE; STEREOISOMERS; COLEOPTERA;

D O I：

10.3762/bjoc.21.38

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tribolium castaneum Herbst is a destructive stored product pest. The aggregation pheromone of this pest was prepared via a new and effective strategy. The key steps include the ring-opening reaction of chiral 2-methyloxirane, the stereospecific inversion of chiral secondary tosylate, Li2CuCl4-catalyzed coupling of tosylate with Grignard reagent, and oxidation with RuCl3/NaIO4.

引用

页码：510 / 514

页数：5

共 36 条

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