Solubility of metal-boron-hydrogen compounds

被引：0

作者：

Nguyen, Thi Phuong Thao ^{[1
]}

Humphries, Terry D. ^{[1
]}

Hagemann, Hans ^{[2
]}

Buckley, Craig E. ^{[1
]}

Jensen, Torben R. ^{[3
]}

Paskevicius, Mark ^{[1
]}

机构：

[1] Curtin Univ, Inst Energy Transit, Dept Phys & Astron, GPO Box U1987, Perth, WA 6845, Australia

[2] Univ Geneva, Dept Chim Phys, 30 Quai E Ansermet, CH-1211 Geneva 4, Switzerland

[3] Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Dept Chem, Langelandsgade 140, DK-8000 Aarhus, Denmark

来源：

DALTON TRANSACTIONS | 2025年 / 54卷 / 03期

基金：

瑞士国家科学基金会; 澳大利亚研究理事会;

关键词：

CRYSTAL-STRUCTURES; PHYSICOCHEMICAL PROPERTIES; MAGNESIUM BOROHYDRIDE; MANGANESE BOROHYDRIDE; SODIUM-BOROHYDRIDE; BORANES; CHEMISTRY; STORAGE; DERIVATIVES; B10H10-2;

D O I：

10.1039/d4dt02256d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Boron-hydrogen compounds are of increasing importance as electrolytes in solid state batteries, for hydrogen storage and possibly as high temperature super conductors. Solvent based methods are of increasing importance to obtain pure products, for purification of materials and also for the synthesis of novel compounds. In this context, the solubility information of several classes of metal-boron-hydrogen compounds such as borohydrides, closo-decahydridodecaborates, closo-dodecahydridododecaborates, arachno- and nido-hydridoborates in typical solvents is vital. This information is currently dispersed in the literature, hence the need to present a cohesive summary and comparison of these properties. This review collects, analyses and discusses the available data to provide inspiration for the future design of new synthesis routes and the discovery of novel materials.

引用

页码：1199 / 1211

页数：13

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