Research Progress of Pt-Based Catalysts toward Cathodic Oxygen Reduction Reactions for Proton Exchange Membrane Fuel Cells

被引:1
作者
Chen, Yue [1 ]
Huang, Zhiyin [1 ]
Yu, Jiefen [1 ]
Wang, Haiyi [1 ]
Qin, Yukuan [1 ]
Xing, Lixin [1 ]
Du, Lei [1 ]
机构
[1] Guangzhou Univ, Huangpu Hydrogen Energy Innovat Ctr, Sch Chem & Chem Engn, Guangzhou 510006, Peoples R China
关键词
proton exchange membrane fuel cell; cathode catalyst layer; oxygen reduction reaction; Pt-based catalysts; HIGH-ENTROPY ALLOYS; SINGLE-ATOM CATALYSTS; ACTIVE-SITE DENSITY; EVOLUTION REACTION; HIGH-PERFORMANCE; N-C; NANOPARTICLE CATALYSTS; PLATINUM NANOPARTICLES; ELECTRONIC-STRUCTURE; HIGHLY EFFICIENT;
D O I
10.3390/catal14090569
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Proton exchange membrane fuel cells (PEMFCs) have been considered by many countries and enterprises because of their cleanness and efficiency. However, due to their high cost and low platinum utilization rate, the commercialization process of PEMFC is severely limited. The cathode catalyst layer (CCL) plays an important role in manipulating the performance and lifespan of PEMFCs, which makes them one of the most significant research focuses in this community. In the CCL, the intrinsic activity and stability of the catalysts determine the performance and lifetime of the catalyst layer. In this paper, the composition and working principle of the PEMFC and cathode catalyst layer are briefly introduced, focusing on Pt-based catalysts for oxygen reduction reactions (ORRs). The research progress of Pt-based catalysts in the past five years is particularly reviewed, mainly concentrating on the development status of emerging Pt-based catalysts which are popular in the current research field, including novel concepts like phase regulation (intermetallic alloys and high-entropy alloys), interface engineering (coupled low-Pt/Pt-free catalysts), and single-atom catalysts. Finally, the future research and development directions of Pt-based ORR catalysts are summarized and prospected.
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页数:34
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