Towards practical all-solid-state batteries: structural engineering innovations for sulfide-based solid electrolytes

被引:0
作者
Roh, Jihun [1 ]
Do, Namgyu [1 ]
Lee, Hyungjin [1 ]
Lee, Sangki [2 ]
Pyun, Jangwook [2 ]
Hong, Seung-Tae [1 ,3 ,4 ]
Chae, Munseok S. [2 ]
机构
[1] Daegu Gyeongbuk Inst Sci & Technol DGIST, Dept Energy Sci & Engn, Daegu 42988, South Korea
[2] Pukyong Natl Univ, Dept Nanotechnol Engn, Pusan 48513, South Korea
[3] Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA
[4] NexeriaTek Inc, Daejeon 34016, South Korea
来源
ENERGY MATERIALS | 2025年 / 5卷 / 02期
基金
新加坡国家研究基金会;
关键词
All-solid-state batteries; sulfide solid electrolyte; super ionic conductor; thio-germanate; LITHIUM IONIC CONDUCTOR; CRYSTAL-STRUCTURE; SUPERIONIC CONDUCTOR; LI2S-P2S5; GLASSES; THIO-LISICON; PHASE-TRANSITION; LI6PS5X X; LI; LI7P3S11; ARGYRODITES;
D O I
10.20517/energymater.2024.219
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Sulfide-based solid electrolytes have emerged as pivotal components for the advancement of next-generation all-solid-state batteries, owing to the battery safety and higher energy density. This paper reviews the recent material innovations in sulfide-based solid electrolytes, focusing on enhancing their ionic conductivities based on an understanding of their crystal structures. Through a comprehensive analysis of current research trends and future perspectives, this review aims to provide a roadmap for the development of more robust and efficient sulfide-based solid electrolytes, which contribute to the realization of safer and higher-performance all-solid-state batteries.
引用
收藏
页数:26
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共 146 条
  • [101] Variation in structure and Li+-ion migration in argyrodite-type Li6PS5X (X = Cl, Br, I) solid electrolytes
    Rayavarapu, Prasada Rao
    Sharma, Neeraj
    Peterson, Vanessa K.
    Adams, Stefan
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (05) : 1807 - 1813
  • [102] Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review
    Reddy, Mogalahalli, V
    Julien, Christian M.
    Mauger, Alain
    Zaghib, Karim
    [J]. NANOMATERIALS, 2020, 10 (08) : 1 - 80
  • [103] IONIC TRANSPORT IN SUPER IONIC CONDUCTORS - THEORETICAL MODEL
    RICE, MJ
    ROTH, WL
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1972, 4 (02) : 294 - +
  • [104] Determination of the crystallization enthalpies of lithium ion conducting alumino-silicate glasses
    Rogez, J
    Knauth, P
    Garnier, A
    Ghobarkar, H
    Schäf, O
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 262 (1-3) : 177 - 182
  • [105] Unraveling Polymorphic Crystal Structures of Li4SiS4 for All-Solid-State Batteries: Enhanced Ionic Conductivity via Aliovalent Sb Substitution
    Roh, Jihun
    Kim, Hyojin
    Lee, Hyungjin
    Bu, Hyeri
    Manjon-Sanz, Alicia
    Kim, Hyungsub
    Hong, Seung-Tae
    [J]. CHEMISTRY OF MATERIALS, 2024, 36 (14) : 6973 - 6984
  • [106] Li2GeS3: Lithium Ionic Conductor with an Unprecedented Structural Type
    Roh, Jihun
    Do, Namgyu
    Manjon-Sanz, Alicia
    Hong, Seung-Tae
    [J]. INORGANIC CHEMISTRY, 2023, 62 (39) : 15856 - 15863
  • [107] Enhanced Li-Ion Conductivity and Air Stability of Sb-Substituted Li4GeS4 toward All-Solid-State Li-Ion Batteries
    Roh, Jihun
    Lyoo, Jeyne
    Hong, Seung-Tae
    [J]. ACS APPLIED ENERGY MATERIALS, 2023, 6 (10) : 5446 - 5455
  • [108] Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery
    Sakuda, Atsushi
    Hayashi, Akitoshi
    Tatsumisago, Masahiro
    [J]. SCIENTIFIC REPORTS, 2013, 3
  • [109] Blocking lithium dendrite growth in solid-state batteries with an ultrathin amorphous Li-La-Zr-O solid electrolyte
    Sastre, Jordi
    Futscher, Moritz H.
    Pompizi, Lea
    Aribia, Abdessalem
    Priebe, Agnieszka
    Overbeck, Jan
    Stiefel, Michael
    Tiwari, Ayodhya N.
    Romanyuk, Yaroslav E.
    [J]. COMMUNICATIONS MATERIALS, 2021, 2 (01)
  • [110] Changing the Static and Dynamic Lattice Effects for the Improvement of the Ionic Transport Properties within the Argyrodite Li6PS5-xSexI (vol 3, pg 9, 2020)
    Schlem, Roman
    Ghidiu, Michael
    Culver, Sean P.
    Hansen, Anna-Lena
    Zeier, Wolfgang G.
    [J]. ACS APPLIED ENERGY MATERIALS, 2020, 3 (04): : 4089 - 4090